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Versatile Preparation of Branched Polylactides by Low-Temperature, Organocatalytic Ring-Opening Polymerization in N-Methylpyrrolidone and Their Surface Degradation Behavior

[Image: see text] We describe how the organocatalytic, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-based lactide ring-opening polymerization can be effectively performed in a very polar solvent, N-methylpyrrolidone (NMP). Due to a low ceiling temperature, this “living” mechanism has been unreported to...

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Detalles Bibliográficos
Autores principales:	Scoponi, Giulia, Francini, Nora, Paradiso, Veronica, Donno, Roberto, Gennari, Arianna, d’Arcy, Richard, Capacchione, Carmine, Athanassiou, Athanassia, Tirelli, Nicola
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8552446/ https://www.ncbi.nlm.nih.gov/pubmed/34720189 http://dx.doi.org/10.1021/acs.macromol.1c01503

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