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Manganese-Catalyzed Dehydrogenative Silylation of Alkenes Following Two Parallel Inner-Sphere Pathways

[Image: see text] We report on an additive-free Mn(I)-catalyzed dehydrogenative silylation of terminal alkenes. The most active precatalyst is the bench-stable alkyl bisphosphine Mn(I) complex fac-[Mn(dippe)(CO)(3)(CH(2)CH(2)CH(3))]. The catalytic process is initiated by migratory insertion of a CO...

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Detalles Bibliográficos
Autores principales:	Weber, Stefan, Glavic, Manuel, Stöger, Berthold, Pittenauer, Ernst, Podewitz, Maren, Veiros, Luis F., Kirchner, Karl
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8554758/ https://www.ncbi.nlm.nih.gov/pubmed/34644064 http://dx.doi.org/10.1021/jacs.1c09175

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