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Reductive Dimerization of CO by a Na/Mg(I) Diamide
[Image: see text] Sodium reduction of [{SiN(Dipp)}Mg] [{SiN(Dipp)} = {CH(2)SiMe(2)N(Dipp)}(2); Dipp = 2,6-i-Pr(2)C(6)H(3)] provides the Mg(I) species, [{SiN(Dipp)}MgNa](2), in which the long Mg–Mg bond (>3.2 Å) is augmented by persistent Na–aryl interactions. Computational assessment indicates th...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8554760/ https://www.ncbi.nlm.nih.gov/pubmed/34652134 http://dx.doi.org/10.1021/jacs.1c09467 |