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Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide

α‐Metallated ylides have revealed themselves to be versatile reagents for the introduction of ylide groups. Herein, we report the synthesis of the thiophosphinoyl and piperidyl (Pip) substituted α‐metallated ylide [Ph(2)(Pip)P=C−P(S)Ph(2)]M (M=Li, Na, K) through a four‐step synthetic procedure start...

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Detalles Bibliográficos
Autores principales: Jörges, Mike, Kroll, Alexander, Kelling, Leif, Gauld, Richard, Mallick, Bert, Huber, Stefan M., Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8562316/
https://www.ncbi.nlm.nih.gov/pubmed/34569718
http://dx.doi.org/10.1002/open.202100187