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Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid

[Image: see text] The reaction of the hexahydride OsH(6)(P(i)Pr(3))(2) with a P,Ge,P-germylene-diphosphine affords an osmium tetrahydride derivative bearing a Ge,P-chelate, which arises from the hydrogenolysis of a P–C(sp(3)) bond. This Os(IV)–Ge(II) compound is a pioneering example of a bifunctiona...

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Detalles Bibliográficos
Autores principales:	Buil, María L., Cabeza, Javier A., Esteruelas, Miguel A., Izquierdo, Susana, Laglera-Gándara, Carlos J., Nicasio, Antonio I., Oñate, Enrique
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8564761/ https://www.ncbi.nlm.nih.gov/pubmed/34657436 http://dx.doi.org/10.1021/acs.inorgchem.1c02893

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