Cargando…

Synthesis, structure and bonding nature of heavy dipnictene radical anions

Cyclic voltammetry (CV) studies of two L(X)Ga-substituted dipnictenes [L(R(2)N)GaE](2) (E = Sb, R = Me 1; E = Bi; R = Et 2; L = HC[C(Me)NDipp](2); Dipp = 2,6-i-Pr(2)C(6)H(3)) showed reversible reduction events. Single electron reduction of 1 and 2 with KC(8) in DME in the presence of benzo-18-crown-...

Descripción completa

Detalles Bibliográficos
Autores principales:	Weinert, Hanns M., Wölper, Christoph, Haak, Julia, Cutsail, George E., Schulz, Stephan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8565390/ https://www.ncbi.nlm.nih.gov/pubmed/34760185 http://dx.doi.org/10.1039/d1sc04230k

Ejemplares similares

Ligand Effects on the Electronic Structure of Heteroleptic Antimony‐Centered Radicals
por: Helling, Christoph, et al.
Publicado: (2020)

Synthesis of distibiranes and azadistibiranes by cycloaddition reactions of distibenes with diazomethanes and azides
por: Weinert, Hanns M., et al.
Publicado: (2022)

From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
por: Ganesamoorthy, Chelladurai, et al.
Publicado: (2018)

Modulating the frontier orbitals of L(X)Ga-substituted diphosphenes [L(X)GaP](2) (X = Cl, Br) and their facile oxidation to radical cations
por: Sharma, Mahendra K., et al.
Publicado: (2022)

A Mechanistic Study on Reactions of Group 13 Diyls LM with Cp*SbX(2): From Stibanyl Radicals to Antimony Hydrides
por: Helling, Christoph, et al.
Publicado: (2020)

From π‐Bonded Gallapnictenes to Nucleophilic, Redox‐Active Metal‐Coordinated Pnictanides
por: Krüger, Julia, et al.
Publicado: (2020)

Redox Activity of Noninnocent 2,2′-Bipyridine in Zinc Complexes: An Experimental and Theoretical Study
por: Li, Bin, et al.
Publicado: (2021)

Supramolecular anion recognition in water: synthesis of hydrogen-bonded supramolecular frameworks
por: Morshedi, Mahbod, et al.
Publicado: (2017)

Taming the stilbene radical anion
por: Sieg, Grégoire, et al.
Publicado: (2022)

Fluorinated β-diketonate complexes M(tfac)(2)(TMEDA) (M = Fe, Ni, Cu, Zn) as precursors for the MOCVD growth of metal and metal oxide thin films
por: Stienen, Christian, et al.
Publicado: (2022)

X-Band Parallel-Mode and Multifrequency Electron Paramagnetic Resonance Spectroscopy of S = 1/2 Bismuth Centers
por: Haak, Julia, et al.
Publicado: (2022)

The power of trichlorosilylation: isolable trisilylated allyl anions, allyl radicals, and allenyl anions
por: Georg, Isabelle, et al.
Publicado: (2021)

The excited-state dynamics of the radical anions of cyanoanthracenes
por: Beckwith, Joseph S., et al.
Publicado: (2021)

Stabilization of benzene radical anion in ammonia clusters
por: Pysanenko, Andriy, et al.
Publicado: (2022)

On the formation of anions: frequency-, angle-, and time-resolved photoelectron imaging of the menadione radical anion
por: Bull, James N., et al.
Publicado: (2015)

Transmembrane anion transport mediated by halogen bonding and hydrogen bonding triazole anionophores
por: Bickerton, Laura E., et al.
Publicado: (2020)

Homoleptic and heteroleptic ketodiiminate zinc complexes for the ROP of cyclic l-lactide
por: Glöckler, Eduard, et al.
Publicado: (2023)

Nonspherical anion sequestration by C–H hydrogen bonding
por: Mirzaei, Saber, et al.
Publicado: (2022)

Hydrogen bond networks in gas-phase complex anions
por: Lai, Zhisheng, et al.
Publicado: (2022)

Radical–anion coupling through reagent design: hydroxylation of aryl halides
por: Greener, Andrew J., et al.
Publicado: (2021)

Synthesis of hydrosilylboronates via the monoborylation of a dihydrosilane Si–H bond and their application for the generation of dialkylhydrosilyl anions
por: Takeuchi, Takumi, et al.
Publicado: (2021)

Multi‐Talented Gallaphosphene for Ga−P−Ga Heteroallyl Cation Generation, CO(2) Storage, and C(sp(3))−H Bond Activation
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions
por: Panetti, Grace B., et al.
Publicado: (2021)

Synthesis and Reactivity of Heteroleptic Ga‐P‐C Allyl Cation Analogues
por: Li, Bin, et al.
Publicado: (2020)

Enhanced voltammetric anion sensing at halogen and hydrogen bonding ferrocenyl SAMs
por: Hein, Robert, et al.
Publicado: (2020)

Persistent radical anion polymers based on naphthalenediimide and a vinylene spacer
por: Debnath, Sashi, et al.
Publicado: (2018)

Disulfide radical anion as a super-reductant in biology and photoredox chemistry
por: Zhu, Qilei, et al.
Publicado: (2023)

Stable radical versus reversible σ-bond formation of (porphyrinyl)dicyanomethyl radicals
por: Adinarayana, B., et al.
Publicado: (2019)

Halogen bonding relay and mobile anion transporters with kinetically controlled chloride selectivity
por: Johnson, Toby G., et al.
Publicado: (2023)

Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp(3))–H bonds
por: Wen, Xin, et al.
Publicado: (2018)

Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters
por: Singh, Anurag, et al.
Publicado: (2022)

The involvement of the trisulfur radical anion in electron-catalyzed sulfur insertion reactions: facile synthesis of benzothiazine derivatives under transition metal-free conditions
por: Gu, Zheng-Yang, et al.
Publicado: (2016)

A rare earth metallocene containing a 2,2′-azopyridyl radical anion
por: Delano IV, Francis, et al.
Publicado: (2021)

Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
por: Hagspiel, Stephan, et al.
Publicado: (2019)

A convenient method for the construction of triazole-bonded chalcone derivatives from acetophenone: Synthesis and free radical scavenging investigation
por: Ullah, Atta, et al.
Publicado: (2023)

Alkynylation of radicals: spotlight on the “Third Way” to transfer triple bonds
por: Le Vaillant, Franck, et al.
Publicado: (2019)

Spontaneous Water Radical Cation Oxidation at Double Bonds in Microdroplets
por: Qiu, Lingqi, et al.
Publicado: (2022)

Radical generation enabled by photoinduced N–O bond fragmentation
por: McClain, Edward J., et al.
Publicado: (2022)

Role of Anions in the Synthesis and Crystal Growth of Selected Semiconductors
por: Matussin, Shaidatul Najihah, et al.
Publicado: (2022)

Superior anion induced shuttling behaviour exhibited by a halogen bonding two station rotaxane
por: Barendt, Timothy A., et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_5bjbmalrabrjkdaa0c6bl229pm