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Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation
Selective C(sp(3)) −H activation is of fundamental importance in processing alkane feedstocks to produce high-value-added chemical products. By virtue of an on-surface synthesis strategy, we report selective cascade dehydrogenation of n-alkane molecules under surface constraints, which yields monodi...
Autores principales: | , , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Oxford University Press
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8566175/ https://www.ncbi.nlm.nih.gov/pubmed/34858613 http://dx.doi.org/10.1093/nsr/nwab093 |
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author | Li, Xuechao Niu, Kaifeng Zhang, Junjie Yu, Xiaojuan Zhang, Haiming Wang, Yuemin Guo, Qing Wang, Pengdong Li, Fangsen Hao, Zhengming Xu, Chaojie Tang, Yanning Xu, Zhichao Lu, Shuai Liu, Peng Xue, Guigu Wei, Yen Chi, Lifeng |
author_facet | Li, Xuechao Niu, Kaifeng Zhang, Junjie Yu, Xiaojuan Zhang, Haiming Wang, Yuemin Guo, Qing Wang, Pengdong Li, Fangsen Hao, Zhengming Xu, Chaojie Tang, Yanning Xu, Zhichao Lu, Shuai Liu, Peng Xue, Guigu Wei, Yen Chi, Lifeng |
author_sort | Li, Xuechao |
collection | PubMed |
description | Selective C(sp(3)) −H activation is of fundamental importance in processing alkane feedstocks to produce high-value-added chemical products. By virtue of an on-surface synthesis strategy, we report selective cascade dehydrogenation of n-alkane molecules under surface constraints, which yields monodispersed all-trans conjugated polyenes with unprecedented length controllability. We are also able to demonstrate the generality of this concept for alkyl-substituted molecules with programmable lengths and diverse functionalities, and more importantly its promising potential in molecular wiring. |
format | Online Article Text |
id | pubmed-8566175 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Oxford University Press |
record_format | MEDLINE/PubMed |
spelling | pubmed-85661752021-12-01 Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation Li, Xuechao Niu, Kaifeng Zhang, Junjie Yu, Xiaojuan Zhang, Haiming Wang, Yuemin Guo, Qing Wang, Pengdong Li, Fangsen Hao, Zhengming Xu, Chaojie Tang, Yanning Xu, Zhichao Lu, Shuai Liu, Peng Xue, Guigu Wei, Yen Chi, Lifeng Natl Sci Rev Chemistry Selective C(sp(3)) −H activation is of fundamental importance in processing alkane feedstocks to produce high-value-added chemical products. By virtue of an on-surface synthesis strategy, we report selective cascade dehydrogenation of n-alkane molecules under surface constraints, which yields monodispersed all-trans conjugated polyenes with unprecedented length controllability. We are also able to demonstrate the generality of this concept for alkyl-substituted molecules with programmable lengths and diverse functionalities, and more importantly its promising potential in molecular wiring. Oxford University Press 2021-05-24 /pmc/articles/PMC8566175/ /pubmed/34858613 http://dx.doi.org/10.1093/nsr/nwab093 Text en © The Author(s) 2021. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Chemistry Li, Xuechao Niu, Kaifeng Zhang, Junjie Yu, Xiaojuan Zhang, Haiming Wang, Yuemin Guo, Qing Wang, Pengdong Li, Fangsen Hao, Zhengming Xu, Chaojie Tang, Yanning Xu, Zhichao Lu, Shuai Liu, Peng Xue, Guigu Wei, Yen Chi, Lifeng Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
title | Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
title_full | Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
title_fullStr | Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
title_full_unstemmed | Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
title_short | Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
title_sort | direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8566175/ https://www.ncbi.nlm.nih.gov/pubmed/34858613 http://dx.doi.org/10.1093/nsr/nwab093 |
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