Polydopamine-Modified Electrospun Polyvinylidene Fluoride Nanofiber Based Flexible Polymer Gel Electrolyte for Highly Stable Dye-Sensitized Solar Cells

[Image: see text] To overcome the drawbacks of solvent evaporation and leakage from the liquid electrolyte in dye-sensitized solar cells (DSSCs), a polymer gel electrolyte (PGE), based on polydopamine (PDA)-modified electrospun polyvinylidene fluoride (PVDF) nanofibers, PDA@PVDF, was prepared and applied in quasi-solid DSSCs (QS-DSSCs). The PDA coating increased the wettability of the liquid electrolyte by improving the distribution of the ionic liquid electrolyte. This, in turn, enhanced the ion conductivity of the PGE as well as the stability of QS-DSSC. The PDA@PVDF nanofiber membrane exhibited a satisfactory ultimate tensile strength of 9.3 MPa with a failure elongation of 130%. Such high toughness provided excellent mechanical support for the PGE. Owing to the unique pore connected structure of nonwoven nanofibers as well as the reduced surface tension with the liquid electrolytes, the PGE-based QS-DSSC retained 95.7% of the short circuit current from the liquid-electrolyte-based DSSC and showed an energy conversion efficiency of 8.26%. No significant impacts were observed for the open-circuit voltage and fill factor. More importantly, the QS-DSSCs using PDA@PVDF-based PGE showed a significantly improved solar cell stability under both indoor and outdoor conditions.