Alumination of aryl methyl ethers: switching between sp(2) and sp(3) C–O bond functionalisation with Pd-catalysis

The reaction of [{(ArNCMe)(2)CH}Al] (Ar = 2,6-di-iso-propylphenyl) with aryl methyl ethers proceeded with alumination of the sp(3) C–O bond. The selectivity of this reaction could be switched by inclusion of a catalyst. In the presence of [Pd(PCy(3))(2)], chemoselective sp(2) C–O bond functionalisat...

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Detalles Bibliográficos
Autores principales: Brown, Ryan K., Hooper, Thomas N., Rekhroukh, Feriel, White, Andrew J. P., Costa, Paulo J., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567294/
https://www.ncbi.nlm.nih.gov/pubmed/34672313
http://dx.doi.org/10.1039/d1cc05408b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567294/
https://www.ncbi.nlm.nih.gov/pubmed/34672313
http://dx.doi.org/10.1039/d1cc05408b

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