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Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue

[Image: see text] Casein (CS) and graphene oxide (GO) were employed for the fabrication of a casein/graphene oxide (CS/GO) aerogel by vacuum freeze drying. Fourier transform infrared spectroscopy, scanning electron microscopy, surface area and micropore analysis (BET), and thermogravimetric analysis...

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Autores principales: Xu, Wenshuo, Li, Yanhui, Wang, Huimin, Du, Qiuju, Li, Meixiu, Sun, Yong, Cui, Mingfei, Li, Liubo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567406/
https://www.ncbi.nlm.nih.gov/pubmed/34746612
http://dx.doi.org/10.1021/acsomega.1c04938
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author Xu, Wenshuo
Li, Yanhui
Wang, Huimin
Du, Qiuju
Li, Meixiu
Sun, Yong
Cui, Mingfei
Li, Liubo
author_facet Xu, Wenshuo
Li, Yanhui
Wang, Huimin
Du, Qiuju
Li, Meixiu
Sun, Yong
Cui, Mingfei
Li, Liubo
author_sort Xu, Wenshuo
collection PubMed
description [Image: see text] Casein (CS) and graphene oxide (GO) were employed for the fabrication of a casein/graphene oxide (CS/GO) aerogel by vacuum freeze drying. Fourier transform infrared spectroscopy, scanning electron microscopy, surface area and micropore analysis (BET), and thermogravimetric analysis were used to characterize the specific surface area, structure, thermal stability, and morphology of the CS/GO aerogel. The influence of experimental parameters such as the GO mass fraction in the aerogel, metering of the adsorbent, pH, contact time, and temperature on the adsorption capacity of the CS/GO aerogel on methylene blue (MB) was also investigated. According to Langmuir isotherm determination, the maximum removal rate of MB from the CS/GO aerogel was 437.29 mg/g when the temperature was 293 K and pH was 8. Through kinetic and thermodynamic studies, it is found that adsorption follows a pseudo-second-order reaction model and is also an exothermic and spontaneous process.
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spelling pubmed-85674062021-11-05 Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue Xu, Wenshuo Li, Yanhui Wang, Huimin Du, Qiuju Li, Meixiu Sun, Yong Cui, Mingfei Li, Liubo ACS Omega [Image: see text] Casein (CS) and graphene oxide (GO) were employed for the fabrication of a casein/graphene oxide (CS/GO) aerogel by vacuum freeze drying. Fourier transform infrared spectroscopy, scanning electron microscopy, surface area and micropore analysis (BET), and thermogravimetric analysis were used to characterize the specific surface area, structure, thermal stability, and morphology of the CS/GO aerogel. The influence of experimental parameters such as the GO mass fraction in the aerogel, metering of the adsorbent, pH, contact time, and temperature on the adsorption capacity of the CS/GO aerogel on methylene blue (MB) was also investigated. According to Langmuir isotherm determination, the maximum removal rate of MB from the CS/GO aerogel was 437.29 mg/g when the temperature was 293 K and pH was 8. Through kinetic and thermodynamic studies, it is found that adsorption follows a pseudo-second-order reaction model and is also an exothermic and spontaneous process. American Chemical Society 2021-10-21 /pmc/articles/PMC8567406/ /pubmed/34746612 http://dx.doi.org/10.1021/acsomega.1c04938 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Xu, Wenshuo
Li, Yanhui
Wang, Huimin
Du, Qiuju
Li, Meixiu
Sun, Yong
Cui, Mingfei
Li, Liubo
Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
title Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
title_full Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
title_fullStr Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
title_full_unstemmed Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
title_short Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
title_sort study on the adsorption performance of casein/graphene oxide aerogel for methylene blue
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567406/
https://www.ncbi.nlm.nih.gov/pubmed/34746612
http://dx.doi.org/10.1021/acsomega.1c04938
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