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Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue
[Image: see text] Casein (CS) and graphene oxide (GO) were employed for the fabrication of a casein/graphene oxide (CS/GO) aerogel by vacuum freeze drying. Fourier transform infrared spectroscopy, scanning electron microscopy, surface area and micropore analysis (BET), and thermogravimetric analysis...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567406/ https://www.ncbi.nlm.nih.gov/pubmed/34746612 http://dx.doi.org/10.1021/acsomega.1c04938 |
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author | Xu, Wenshuo Li, Yanhui Wang, Huimin Du, Qiuju Li, Meixiu Sun, Yong Cui, Mingfei Li, Liubo |
author_facet | Xu, Wenshuo Li, Yanhui Wang, Huimin Du, Qiuju Li, Meixiu Sun, Yong Cui, Mingfei Li, Liubo |
author_sort | Xu, Wenshuo |
collection | PubMed |
description | [Image: see text] Casein (CS) and graphene oxide (GO) were employed for the fabrication of a casein/graphene oxide (CS/GO) aerogel by vacuum freeze drying. Fourier transform infrared spectroscopy, scanning electron microscopy, surface area and micropore analysis (BET), and thermogravimetric analysis were used to characterize the specific surface area, structure, thermal stability, and morphology of the CS/GO aerogel. The influence of experimental parameters such as the GO mass fraction in the aerogel, metering of the adsorbent, pH, contact time, and temperature on the adsorption capacity of the CS/GO aerogel on methylene blue (MB) was also investigated. According to Langmuir isotherm determination, the maximum removal rate of MB from the CS/GO aerogel was 437.29 mg/g when the temperature was 293 K and pH was 8. Through kinetic and thermodynamic studies, it is found that adsorption follows a pseudo-second-order reaction model and is also an exothermic and spontaneous process. |
format | Online Article Text |
id | pubmed-8567406 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-85674062021-11-05 Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue Xu, Wenshuo Li, Yanhui Wang, Huimin Du, Qiuju Li, Meixiu Sun, Yong Cui, Mingfei Li, Liubo ACS Omega [Image: see text] Casein (CS) and graphene oxide (GO) were employed for the fabrication of a casein/graphene oxide (CS/GO) aerogel by vacuum freeze drying. Fourier transform infrared spectroscopy, scanning electron microscopy, surface area and micropore analysis (BET), and thermogravimetric analysis were used to characterize the specific surface area, structure, thermal stability, and morphology of the CS/GO aerogel. The influence of experimental parameters such as the GO mass fraction in the aerogel, metering of the adsorbent, pH, contact time, and temperature on the adsorption capacity of the CS/GO aerogel on methylene blue (MB) was also investigated. According to Langmuir isotherm determination, the maximum removal rate of MB from the CS/GO aerogel was 437.29 mg/g when the temperature was 293 K and pH was 8. Through kinetic and thermodynamic studies, it is found that adsorption follows a pseudo-second-order reaction model and is also an exothermic and spontaneous process. American Chemical Society 2021-10-21 /pmc/articles/PMC8567406/ /pubmed/34746612 http://dx.doi.org/10.1021/acsomega.1c04938 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Xu, Wenshuo Li, Yanhui Wang, Huimin Du, Qiuju Li, Meixiu Sun, Yong Cui, Mingfei Li, Liubo Study on the Adsorption Performance of Casein/Graphene Oxide Aerogel for Methylene Blue |
title | Study on the Adsorption Performance of Casein/Graphene
Oxide Aerogel for Methylene Blue |
title_full | Study on the Adsorption Performance of Casein/Graphene
Oxide Aerogel for Methylene Blue |
title_fullStr | Study on the Adsorption Performance of Casein/Graphene
Oxide Aerogel for Methylene Blue |
title_full_unstemmed | Study on the Adsorption Performance of Casein/Graphene
Oxide Aerogel for Methylene Blue |
title_short | Study on the Adsorption Performance of Casein/Graphene
Oxide Aerogel for Methylene Blue |
title_sort | study on the adsorption performance of casein/graphene
oxide aerogel for methylene blue |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567406/ https://www.ncbi.nlm.nih.gov/pubmed/34746612 http://dx.doi.org/10.1021/acsomega.1c04938 |
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