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Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature
A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl(−) + H(2)S + CO(2) at 180 °C. By analyzing the weight loss of steel exposed to...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer International Publishing
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567579/ https://www.ncbi.nlm.nih.gov/pubmed/34732232 http://dx.doi.org/10.1186/s13065-021-00784-9 |
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author | Zhuoke, Li Jun, Cao Ting, Mao Dan, Ni |
author_facet | Zhuoke, Li Jun, Cao Ting, Mao Dan, Ni |
author_sort | Zhuoke, Li |
collection | PubMed |
description | A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl(−) + H(2)S + CO(2) at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. [Image: see text] |
format | Online Article Text |
id | pubmed-8567579 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Springer International Publishing |
record_format | MEDLINE/PubMed |
spelling | pubmed-85675792021-11-04 Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature Zhuoke, Li Jun, Cao Ting, Mao Dan, Ni BMC Chem Research Article A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl(−) + H(2)S + CO(2) at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. [Image: see text] Springer International Publishing 2021-11-03 /pmc/articles/PMC8567579/ /pubmed/34732232 http://dx.doi.org/10.1186/s13065-021-00784-9 Text en © The Author(s) 2021 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/ (https://creativecommons.org/publicdomain/zero/1.0/) ) applies to the data made available in this article, unless otherwise stated in a credit line to the data. |
spellingShingle | Research Article Zhuoke, Li Jun, Cao Ting, Mao Dan, Ni Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature |
title | Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature |
title_full | Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature |
title_fullStr | Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature |
title_full_unstemmed | Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature |
title_short | Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H(2)S and CO(2) at high temperature |
title_sort | synthesis of bimannich base with thiazole and its corrosion inhibition effect on h(2)s and co(2) at high temperature |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8567579/ https://www.ncbi.nlm.nih.gov/pubmed/34732232 http://dx.doi.org/10.1186/s13065-021-00784-9 |
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