Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere

[Image: see text] Enzymes exert control over the reactivity of metal centers with precise tuning of the secondary coordination sphere of active sites. One particularly elegant illustration of this principle is in the controlled delivery of proton and electron equivalents in order to activate abundan...

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Detalles Bibliográficos
Autores principales: Jesse, Kate A., Anferov, Sophie W., Collins, Kelsey A., Valdez-Moreira, Juan A., Czaikowski, Maia E., Filatov, Alexander S., Anderson, John S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8569801/
https://www.ncbi.nlm.nih.gov/pubmed/34698493
http://dx.doi.org/10.1021/jacs.1c06911

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8569801/
https://www.ncbi.nlm.nih.gov/pubmed/34698493
http://dx.doi.org/10.1021/jacs.1c06911

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