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Does the Configuration at the Metal Matter in Noyori–Ikariya Type Asymmetric Transfer Hydrogenation Catalysts?

[Image: see text] Noyori–Ikariya type [(arene)RuCl(TsDPEN)] (TsDPEN, sulfonated diphenyl ethylenediamine) complexes are widely used C=O and C=N reduction catalysts that produce chiral alcohols and amines via a key ruthenium–hydride intermediate that determines the stereochemistry of the product. Whe...

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Detalles Bibliográficos
Autores principales:	Hall, Andrew M. R., Berry, Daniel B. G., Crossley, Jaime N., Codina, Anna, Clegg, Ian, Lowe, John P., Buchard, Antoine, Hintermair, Ulrich
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8576814/ https://www.ncbi.nlm.nih.gov/pubmed/34777911 http://dx.doi.org/10.1021/acscatal.1c03636

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