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per-Hydroxylated Prism[n]arenes: Supramolecularly Assisted Demethylation of Methoxy-Prism[5]arene
[Image: see text] Methoxy-prism[5]arene PrS[5](Me) is demethylated by a supramolecularly assisted reaction. In the presence of a tetramethylammonium cation, PrS[5](Me) is demethylated by BBr(3) in high yield, while in its absence a 55/40 mixture of PrS[5](OH)/PrS[6](OH) is formed. The dealkylation o...
Autores principales: | Del Regno, Rocco, Della Sala, Paolo, Picariello, Davide, Talotta, Carmen, Spinella, Aldo, Neri, Placido, Gaeta, Carmine |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8576831/ https://www.ncbi.nlm.nih.gov/pubmed/34633199 http://dx.doi.org/10.1021/acs.orglett.1c02800 |
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