Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex

N-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex induced by v...

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Autores principales: Xiang, Jing, Peng, Min, Pan, Yi, Luo, Li-Juan, Cheng, Shun-Cheung, Jin, Xin-Xin, Yiu, Shek-Man, Man, Wai-Lun, Ko, Chi-Chiu, Lau, Kai-Chung, Lau, Tai-Chu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8580045/
https://www.ncbi.nlm.nih.gov/pubmed/34881000
http://dx.doi.org/10.1039/d1sc04369b
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author Xiang, Jing
Peng, Min
Pan, Yi
Luo, Li-Juan
Cheng, Shun-Cheung
Jin, Xin-Xin
Yiu, Shek-Man
Man, Wai-Lun
Ko, Chi-Chiu
Lau, Kai-Chung
Lau, Tai-Chu
author_facet Xiang, Jing
Peng, Min
Pan, Yi
Luo, Li-Juan
Cheng, Shun-Cheung
Jin, Xin-Xin
Yiu, Shek-Man
Man, Wai-Lun
Ko, Chi-Chiu
Lau, Kai-Chung
Lau, Tai-Chu
author_sort Xiang, Jing
collection PubMed
description N-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex induced by visible light.
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spelling pubmed-85800452021-12-07 Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex Xiang, Jing Peng, Min Pan, Yi Luo, Li-Juan Cheng, Shun-Cheung Jin, Xin-Xin Yiu, Shek-Man Man, Wai-Lun Ko, Chi-Chiu Lau, Kai-Chung Lau, Tai-Chu Chem Sci Chemistry N-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex induced by visible light. The Royal Society of Chemistry 2021-10-09 /pmc/articles/PMC8580045/ /pubmed/34881000 http://dx.doi.org/10.1039/d1sc04369b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Xiang, Jing
Peng, Min
Pan, Yi
Luo, Li-Juan
Cheng, Shun-Cheung
Jin, Xin-Xin
Yiu, Shek-Man
Man, Wai-Lun
Ko, Chi-Chiu
Lau, Kai-Chung
Lau, Tai-Chu
Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
title Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
title_full Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
title_fullStr Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
title_full_unstemmed Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
title_short Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
title_sort visible light-induced oxidative n-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8580045/
https://www.ncbi.nlm.nih.gov/pubmed/34881000
http://dx.doi.org/10.1039/d1sc04369b
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