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When SF(5) outplays CF(3): effects of pentafluorosulfanyl decorated scorpionates on copper

Polyfluorinated, electron-withdrawing, and sterically demanding supporting ligands are of significant value in chemistry. Here we report the assembly and use of a bis(pyrazolyl)borate, [Ph(2)B(3-(SF(5))Pz)(2)](−) that combines all such features, and involves underutilized pentafluorosulfanyl substit...

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Detalles Bibliográficos
Autores principales:	Noonikara-Poyil, Anurag, Muñoz-Castro, Alvaro, Boretskyi, Andrii, Mykhailiuk, Pavel K., Dias, H. V. Rasika
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8580053/ https://www.ncbi.nlm.nih.gov/pubmed/34881014 http://dx.doi.org/10.1039/d1sc04846e

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