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Synthesis and electronic structure analysis of the actinide allenylidenes, [{(NR(2))(3)}An(CCCPh(2))](−) (An = U, Th; R = SiMe(3))

The reaction of [AnCl(NR(2))(3)] (An = U, Th, R = SiMe(3)) with in situ generated lithium-3,3-diphenylcyclopropene results in the formation of [{(NR(2))(3)}An(CH[double bond, length as m-dash]C[double bond, length as m-dash]CPh(2))] (An = U, 1; Th, 2) in good yields after work-up. Deprotonation of 1...

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Detalles Bibliográficos
Autores principales:	Kent, Greggory T., Yu, Xiaojuan, Wu, Guang, Autschbach, Jochen, Hayton, Trevor W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8580070/ https://www.ncbi.nlm.nih.gov/pubmed/34880989 http://dx.doi.org/10.1039/d1sc04666g

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