Cargando…

Substituent Effects on the Basicity of Patriscabrin A and Lettucenin A: Evolution Favors the Aromatic?

[Image: see text] Basicities for derivatives of patriscabrin A and lettucenin A were calculated with density functional theory. A significant correlation is observed between the basicity and Hammett σ parameters. Protonation increases the aromatic character of the cyclic moieties of each natural pro...

Descripción completa

Detalles Bibliográficos
Autores principales:	Prasad, Supreeth, Tantillo, Dean J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8582057/ https://www.ncbi.nlm.nih.gov/pubmed/34778640 http://dx.doi.org/10.1021/acsomega.1c04051

Ejemplares similares

Role of Benzoic Acid and Lettucenin A in the Defense Response of Lettuce against Soil-Borne Pathogens
por: Windisch, Saskia, et al.
Publicado: (2021)

Substituent effects on aromatic interactions in water
por: Tobajas-Curiel, Gloria, et al.
Publicado: (2023)

Substituent Effects and the Energetics of Noncatalyzed Aryl Halide Aminations: A Theoretical Investigation
por: Prasad, Supreeth, et al.
Publicado: (2021)

Substituent Effect versus Aromaticity—A Curious Case of Fulvene Derivatives
por: Wieczorkiewicz, Pawel A., et al.
Publicado: (2023)

Substituted adenine quartets: interplay between substituent effect, hydrogen bonding, and aromaticity
por: Szatylowicz, Halina, et al.
Publicado: (2020)

Mechanistic Origin of Favorable Substituent Effects in Excellent Cu Cyclam Based HNO Sensors
por: Shi, Yelu, et al.
Publicado: (2022)

Substituent Effects in Tetrel Bonds Involving Aromatic Silane Derivatives: An ab initio Study
por: Burguera, Sergi, et al.
Publicado: (2023)

Fluoromaticity: The Molecular Orbital Contributions of Fluorine Substituents to the π-Systems of Aromatic Rings
por: Fuhrer, Timothy J., et al.
Publicado: (2021)

A facile synthetic route to benzimidazolium salts bearing bulky aromatic N-substituents
por: Grieco, Gabriele, et al.
Publicado: (2015)

Effect of Methoxy Substituents on the Activation Barriers of the Glutathione Peroxidase-Like Mechanism of an Aromatic Cyclic Seleninate
por: Bayse, Craig A., et al.
Publicado: (2015)

Tetrel Bond between 6-OTX(3)-Fulvene and NH(3): Substituents and Aromaticity
por: Hou, Ming-Chang, et al.
Publicado: (2018)

Mutual Relations between Substituent Effect, Hydrogen Bonding, and Aromaticity in Adenine-Uracil and Adenine-Adenine Base Pairs †
por: Wieczorkiewicz, Paweł A., et al.
Publicado: (2020)

Self-Assembly and Drug Release Capacities of Organogels via Some Amide Compounds with Aromatic Substituent Headgroups
por: Zhang, Lexin, et al.
Publicado: (2016)

Controllable fluorescence via tuning the m-substituents of added aromatic molecules in a pyrene derivative-decorated porous skeleton
por: Wu, Jianbin, et al.
Publicado: (2019)

Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution
por: Wei, Yang, et al.
Publicado: (2017)

Quantifying Through‐Space Substituent Effects
por: Burns, Rebecca J., et al.
Publicado: (2020)

Controlled Allocation of Aromatic/Aliphatic Substituents to Polysaccharides and Lignin in Sugarcane Bagasse via Successive Homogeneous Transesterification Using Ionic Liquid
por: Suzuki, Shiori, et al.
Publicado: (2023)

Effect of a Substituent on the Properties of Salicylaldehyde Hydrazone Derivatives
por: Hoelm, Marta, et al.
Publicado: (2023)

Substituent Effect in the Cation Radicals of Monosubstituted Benzenes
por: Dobrowolski, Jan Cz., et al.
Publicado: (2021)

Substituent Effects on the Radical Scavenging Activity of Isoflavonoid
por: Zheng, Yan-Zhen, et al.
Publicado: (2019)

The Substituent Effect on the Radical Scavenging Activity of Apigenin
por: Zheng, Yan-Zhen, et al.
Publicado: (2018)

Substituent Effects on the Stability and Antioxidant Activity of Spirodiazaselenuranes
por: Lamani, Devappa S., et al.
Publicado: (2015)

Substituent effect on inter-ring interaction in paracyclophanes
por: Majerz, Irena, et al.
Publicado: (2019)

Ferrocenoyl-adenines: substituent effects on regioselective acylation
por: Toma, Mateja, et al.
Publicado: (2022)

QSAR analysis of substituent effects on tambjamine anion transporters
por: Knight, Nicola J., et al.
Publicado: (2016)

Metabolism and toxicology of pyrethroids with dihalovinyl substituents.
por: Ruzo, L O, et al.
Publicado: (1977)

Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand
por: Khade, Rahul L., et al.
Publicado: (2015)

Nearest-Neighbour and Non-Nearest-Neighbour Non-Covalent Interactions between Substituents in the Aromatic Systems: Experimental and Theoretical Investigation of Functionally Substituted Benzophenones
por: Samarov, Artemiy A., et al.
Publicado: (2022)

First-principles studies of substituent effects on squaraine dyes
por: Barcenas, German, et al.
Publicado: (2021)

Substituent Effects on the [N–I–N](+) Halogen Bond
por: Carlsson, Anna-Carin C., et al.
Publicado: (2016)

Classical and Reverse Substituent Effects in Substituted Anthrol Derivatives
por: Szatylowicz, Halina, et al.
Publicado: (2019)

Substituent effects on paratropicity and diatropicity in π-extended hexapyrrolohexaazacoronene
por: Takase, Masayoshi, et al.
Publicado: (2023)

Remarkable effect of alkynyl substituents on the fluorescence properties of a BN-phenanthrene
por: Abengózar, Alberto, et al.
Publicado: (2019)

Unraveling substituent effects on the glass transition temperatures of biorenewable polyesters
por: Yu, Xiaopeng, et al.
Publicado: (2018)

NMR spectroscopy of basic/aromatic amino acid clusters in membrane proteins
por: Zhang, Wenyi, et al.
Publicado: (2006)

Experimental Quantum Chemistry: A Hammett‐inspired Fingerprinting of Substituent Effects
por: Sessa, Francesco, et al.
Publicado: (2021)

Effect of a Substituent in the Fourth Position on the Optical Properties of 2-Oxonicotinonitriles
por: Sorokin, S. P., et al.
Publicado: (2022)

Progesterone hypersensitivity: Case report with favorable evolution
por: Senila, Simona C., et al.
Publicado: (2019)

Effect of Substituents of Cerium Pyrazolates and Pyrrolates on Carbon Dioxide Activation
por: Bayer, Uwe, et al.
Publicado: (2021)

Effect of the Solvent and Substituent on Tautomeric Preferences of Amine-Adenine Tautomers
por: Jezuita, Anna, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_lnhqgbt3dk8cimtarsgots04ue