Diamond Coating Reduces Nuclear Fuel Rod Corrosion at Accidental Temperatures: The Role of Surface Electrochemistry and Semiconductivity

If we want to decrease the probability of accidents in nuclear reactors, we must control the surface corrosion of the fuel rods. In this work we used a diamond coating containing <60% diamond and >40% sp(2) “soft” carbon phase to protect Zr alloy fuel rods (ZIRLO(®)) against corrosion in steam at temperatures from 850 °C to 1000 °C. A diamond coating was grown in a pulse microwave plasma chemical vapor deposition apparatus and made a strong barrier against hydrogen uptake into ZIRLO(®) (ZIRLO) under all tested conditions. The coating also reduced ZIRLO corrosion in hot steam at 850 °C (for 60 min) and at 900 °C (for 30 min). However, the protective ability of the diamond coating decreased after 20 min in 1000 °C hot steam. The main goal of this work was to explain how diamond and sp(2) “soft” carbon affect the ZIRLO fuel rod surface electrochemistry and semi conductivity and how these parameters influence the hot steam ZIRLO corrosion process. To achieve this goal, theoretical and experimental methods (scanning electron microscopy, Raman spectroscopy, electrochemical impedance spectroscopy, carrier gas hot extraction, oxidation kinetics, ab initio calculations) were applied. Deep understanding of ZIRLO surface processes and states enable us to reduce accidental temperature corrosion in nuclear reactors.