Alkaloids and Selected Topics in Their Thermochemistry

Alkaloid chemistry is varied and complex. Many alkaloids attract a great deal of interest because of their physiological activity, yet surprisingly little is known about the thermochemistry of these compounds, especially in the gas phase. In this paper, we investigate the thermochemical characterist...

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Detalles Bibliográficos
Autores principales: Ponikvar-Svet, Maja, Zeiger, Diana N., Liebman, Joel F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587110/
https://www.ncbi.nlm.nih.gov/pubmed/34771124
http://dx.doi.org/10.3390/molecules26216715
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author Ponikvar-Svet, Maja
Zeiger, Diana N.
Liebman, Joel F.
author_facet Ponikvar-Svet, Maja
Zeiger, Diana N.
Liebman, Joel F.
author_sort Ponikvar-Svet, Maja
collection PubMed
description Alkaloid chemistry is varied and complex. Many alkaloids attract a great deal of interest because of their physiological activity, yet surprisingly little is known about the thermochemistry of these compounds, especially in the gas phase. In this paper, we investigate the thermochemical characteristics, specifically demethoxylation enthalpies rather than those derived from trans-methoxylation reactions, of a series of biologically relevant alkaloids in their condensed phase.
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spelling pubmed-85871102021-11-13 Alkaloids and Selected Topics in Their Thermochemistry Ponikvar-Svet, Maja Zeiger, Diana N. Liebman, Joel F. Molecules Review Alkaloid chemistry is varied and complex. Many alkaloids attract a great deal of interest because of their physiological activity, yet surprisingly little is known about the thermochemistry of these compounds, especially in the gas phase. In this paper, we investigate the thermochemical characteristics, specifically demethoxylation enthalpies rather than those derived from trans-methoxylation reactions, of a series of biologically relevant alkaloids in their condensed phase. MDPI 2021-11-06 /pmc/articles/PMC8587110/ /pubmed/34771124 http://dx.doi.org/10.3390/molecules26216715 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Ponikvar-Svet, Maja
Zeiger, Diana N.
Liebman, Joel F.
Alkaloids and Selected Topics in Their Thermochemistry
title Alkaloids and Selected Topics in Their Thermochemistry
title_full Alkaloids and Selected Topics in Their Thermochemistry
title_fullStr Alkaloids and Selected Topics in Their Thermochemistry
title_full_unstemmed Alkaloids and Selected Topics in Their Thermochemistry
title_short Alkaloids and Selected Topics in Their Thermochemistry
title_sort alkaloids and selected topics in their thermochemistry
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587110/
https://www.ncbi.nlm.nih.gov/pubmed/34771124
http://dx.doi.org/10.3390/molecules26216715
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