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Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
The title four-coordinate mononuclear complex, [Hg(C(3)H(5)OS(2))(2)(C(6)H(16)N(2))] or [Hg(C(3)H(5)OS(2))(2)(tmeda)] (tmeda: N,N,N′,N′-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The Hg(II) ion is coordinated to two N atoms of the N,N,N′,N′-tetramethylethylenediamin...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587978/ https://www.ncbi.nlm.nih.gov/pubmed/34868649 http://dx.doi.org/10.1107/S2056989021010549 |
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author | Qadir, Adnan M. Kansiz, Sevgi Dege, Necmi Saif, Eiad |
author_facet | Qadir, Adnan M. Kansiz, Sevgi Dege, Necmi Saif, Eiad |
author_sort | Qadir, Adnan M. |
collection | PubMed |
description | The title four-coordinate mononuclear complex, [Hg(C(3)H(5)OS(2))(2)(C(6)H(16)N(2))] or [Hg(C(3)H(5)OS(2))(2)(tmeda)] (tmeda: N,N,N′,N′-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The Hg(II) ion is coordinated to two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, molecules are linked by weak C—H⋯S hydrogen bonds, forming a two-dimensional supramolecular architecture in the ab plane. The most important contributions for the crystal packing are from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) interactions. |
format | Online Article Text |
id | pubmed-8587978 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-85879782021-12-02 Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) Qadir, Adnan M. Kansiz, Sevgi Dege, Necmi Saif, Eiad Acta Crystallogr E Crystallogr Commun Research Communications The title four-coordinate mononuclear complex, [Hg(C(3)H(5)OS(2))(2)(C(6)H(16)N(2))] or [Hg(C(3)H(5)OS(2))(2)(tmeda)] (tmeda: N,N,N′,N′-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The Hg(II) ion is coordinated to two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, molecules are linked by weak C—H⋯S hydrogen bonds, forming a two-dimensional supramolecular architecture in the ab plane. The most important contributions for the crystal packing are from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) interactions. International Union of Crystallography 2021-10-19 /pmc/articles/PMC8587978/ /pubmed/34868649 http://dx.doi.org/10.1107/S2056989021010549 Text en © Qadir et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Qadir, Adnan M. Kansiz, Sevgi Dege, Necmi Saif, Eiad Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) |
title | Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) |
title_full | Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) |
title_fullStr | Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) |
title_short | Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II) |
title_sort | crystal structure and hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](n,n,n′,n′-tetramethylethane-1,2-diamine)mercury(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587978/ https://www.ncbi.nlm.nih.gov/pubmed/34868649 http://dx.doi.org/10.1107/S2056989021010549 |
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