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Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)

The title four-coordinate mononuclear complex, [Hg(C(3)H(5)OS(2))(2)(C(6)H(16)N(2))] or [Hg(C(3)H(5)OS(2))(2)(tmeda)] (tmeda: N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine), has a distorted tetra­hedral geometry. The Hg(II) ion is coordinated to two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amin...

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Autores principales: Qadir, Adnan M., Kansiz, Sevgi, Dege, Necmi, Saif, Eiad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587978/
https://www.ncbi.nlm.nih.gov/pubmed/34868649
http://dx.doi.org/10.1107/S2056989021010549
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author Qadir, Adnan M.
Kansiz, Sevgi
Dege, Necmi
Saif, Eiad
author_facet Qadir, Adnan M.
Kansiz, Sevgi
Dege, Necmi
Saif, Eiad
author_sort Qadir, Adnan M.
collection PubMed
description The title four-coordinate mononuclear complex, [Hg(C(3)H(5)OS(2))(2)(C(6)H(16)N(2))] or [Hg(C(3)H(5)OS(2))(2)(tmeda)] (tmeda: N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine), has a distorted tetra­hedral geometry. The Hg(II) ion is coordinated to two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, mol­ecules are linked by weak C—H⋯S hydrogen bonds, forming a two-dimensional supra­molecular architecture in the ab plane. The most important contributions for the crystal packing are from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) inter­actions.
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spelling pubmed-85879782021-12-02 Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II) Qadir, Adnan M. Kansiz, Sevgi Dege, Necmi Saif, Eiad Acta Crystallogr E Crystallogr Commun Research Communications The title four-coordinate mononuclear complex, [Hg(C(3)H(5)OS(2))(2)(C(6)H(16)N(2))] or [Hg(C(3)H(5)OS(2))(2)(tmeda)] (tmeda: N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine), has a distorted tetra­hedral geometry. The Hg(II) ion is coordinated to two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, mol­ecules are linked by weak C—H⋯S hydrogen bonds, forming a two-dimensional supra­molecular architecture in the ab plane. The most important contributions for the crystal packing are from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) inter­actions. International Union of Crystallography 2021-10-19 /pmc/articles/PMC8587978/ /pubmed/34868649 http://dx.doi.org/10.1107/S2056989021010549 Text en © Qadir et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Qadir, Adnan M.
Kansiz, Sevgi
Dege, Necmi
Saif, Eiad
Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)
title Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)
title_full Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)
title_fullStr Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)
title_short Crystal structure and Hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine)­mercury(II)
title_sort crystal structure and hirshfeld surface analysis of bis­[(eth­oxy­methane­thio­yl)sulfanido](n,n,n′,n′-tetra­methyl­ethane-1,2-di­amine)­mercury(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587978/
https://www.ncbi.nlm.nih.gov/pubmed/34868649
http://dx.doi.org/10.1107/S2056989021010549
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