Crystal structure and Hirshfeld surface analysis of (Z)-2-{[(2,4-dimethylphenyl)imino]methyl}-4-methylphenol
The title compound, C(16)H(17)NO, is a Schiff base that exists in the enol–imine tautomeric form and adopts a Z configuration. The molecule is non-planar, with the twisted rings making a dihedral angle of 39.92 (4)°. The intramolecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587990/ https://www.ncbi.nlm.nih.gov/pubmed/34868641 http://dx.doi.org/10.1107/S2056989021010215 |
Sumario: | The title compound, C(16)H(17)NO, is a Schiff base that exists in the enol–imine tautomeric form and adopts a Z configuration. The molecule is non-planar, with the twisted rings making a dihedral angle of 39.92 (4)°. The intramolecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, molecules are linked by C—H⋯π interactions and very weak π-π stacking interactions also help to consolidate the crystal packing. A Hirshfeld surface analysis was performed to investigate the contributions of different intermolecular contacts within the supramolecular structure. The major contributions are from H⋯H (65%), C⋯H (19.2%) and O⋯H (6.6%) interactions. |
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