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Cyclo‐Dipnictadialanes

Using the Al(I) precursor Cp(3t)Al in conjunction with triphosphiranes (PAr)(3) (Ar=Mes, Dip, Tip) we have succeeded in preparing Lewis base‐free cyclic diphosphadialanes with both the Al and P atoms bearing three substituents. Using the sterically more demanding Dip and Tip substituents the first 1...

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Detalles Bibliográficos
Autores principales: Nees, Samuel, Fantuzzi, Felipe, Wellnitz, Tim, Fischer, Malte, Siewert, Jan‐Erik, Goettel, James T., Hofmann, Alexander, Härterich, Marcel, Braunschweig, Holger, Hering‐Junghans, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596407/
https://www.ncbi.nlm.nih.gov/pubmed/34478231
http://dx.doi.org/10.1002/anie.202111121