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A Copper(I) Complex with Two Unpaired Electrons, Synthesised by Oxidation of a Copper(II) Complex with Two Redox‐Active Ligands

Two homoleptic copper(II) complexes [Cu(L1)(2)] and [Cu(L2)(2)] with anionic redox‐active ligands were synthesised, one with urea azine (L1) and the other with thio‐urea azine (L2) ligands. One‐electron oxidation of the complexes initiates an unprecedented redox‐induced electron transfer process, le...

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Detalles Bibliográficos
Autores principales: Werr, Marco, Kaifer, Elisabeth, Enders, Markus, Asyuda, Andika, Zharnikov, Michael, Himmel, Hans‐Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596453/
https://www.ncbi.nlm.nih.gov/pubmed/34423532
http://dx.doi.org/10.1002/anie.202109367