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The Anionic Pathway in the Nickel‐Catalysed Cross‐Coupling of Aryl Ethers
The Ni‐catalysed cross‐coupling of aryl ethers is a powerful method to forge new C−C and C−heteroatom bonds. However, the inert C(sp(2))−O bond means that a canonical mechanism that relies on the oxidative addition of the aryl ether to a Ni(0) centre is thermodynamically and kinetically unfavourable...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596537/ https://www.ncbi.nlm.nih.gov/pubmed/34469021 http://dx.doi.org/10.1002/anie.202110785 |