Platinum Indolylphosphine Fluorido and Polyfluorido Complexes: An Interplay between Cyclometallation, Fluoride Migration, and Hydrogen Bonding

The reaction of [PtCl(2)(COD)] (COD=1,5‐cyclooctadiene) with diisopropyl‐2‐(3‐methyl)indolylphosphine (iPr(2)P(C(9)H(8)N)) led to the formation of the platinum(ii) chlorido complexes, cis‐[PtCl(2){iPr(2)P(C(9)H(8)N)}(2)] (1) and trans‐[PtCl(2){iPr(2)P(C(9)H(8)N)}(2)] (2). The cis‐complex 1 reacted w...

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Detalles Bibliográficos
Autores principales: Sander, Stefan, Müller, Robert, Ahrens, Mike, Kaupp, Martin, Braun, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596594/
https://www.ncbi.nlm.nih.gov/pubmed/34337795
http://dx.doi.org/10.1002/chem.202102451

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596594/
https://www.ncbi.nlm.nih.gov/pubmed/34337795
http://dx.doi.org/10.1002/chem.202102451

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