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Platinum Indolylphosphine Fluorido and Polyfluorido Complexes: An Interplay between Cyclometallation, Fluoride Migration, and Hydrogen Bonding
The reaction of [PtCl(2)(COD)] (COD=1,5‐cyclooctadiene) with diisopropyl‐2‐(3‐methyl)indolylphosphine (iPr(2)P(C(9)H(8)N)) led to the formation of the platinum(ii) chlorido complexes, cis‐[PtCl(2){iPr(2)P(C(9)H(8)N)}(2)] (1) and trans‐[PtCl(2){iPr(2)P(C(9)H(8)N)}(2)] (2). The cis‐complex 1 reacted w...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596594/ https://www.ncbi.nlm.nih.gov/pubmed/34337795 http://dx.doi.org/10.1002/chem.202102451 |