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A Zwitterionic Heterobimetallic Gold–Iron Complex Supported by Bis(N‐Heterocyclic Imine)Silyliumylidene

The facile synthesis of the first bis‐N‐heterocyclic imine‐stabilized chlorosilyliumylidene 1 is reported. Remarkably, consecutive reaction of 1 with PPh(3)AuCl and K(2)Fe(CO)(4) gives rise to the unique heterobimetallic complex 1,2‐((Mes)NHI)(2)‐C(2)H(4)‐ClSiAuFe(CO)(4) (4). The overall neutral com...

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Detalles Bibliográficos
Autores principales: Hanusch, Franziska, Munz, Dominik, Sutter, Jörg, Meyer, Karsten, Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596601/
https://www.ncbi.nlm.nih.gov/pubmed/34411406
http://dx.doi.org/10.1002/anie.202108146