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Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C−COCl Bond Cleavage

Here we report a palladium‐catalysed difunctionalisation of unsaturated C−C bonds with acid chlorides. Formally, the C−COCl bond of an acid chloride is cleaved and added, with complete atom economy, across either strained alkenes or a tethered alkyne to generate new acid chlorides. The transformatio...

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Detalles Bibliográficos
Autores principales: Denton, Elliott H., Lee, Yong Ho, Roediger, Sven, Boehm, Philip, Fellert, Maximilian, Morandi, Bill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596603/
https://www.ncbi.nlm.nih.gov/pubmed/34432940
http://dx.doi.org/10.1002/anie.202108818