Isolable Geminal Bisgermenolates: A New Synthon in Organometallic Chemistry

We have synthesized the first isolable geminal bisenolates L(2)K(2)Ge[(CO)R](2) (R=2,4,6‐trimethylphenyl (2 a,b), L=THF for (2 a) or [18]‐crown‐6 for (2 b)), a new synthon for the synthesis of organometallic reagents. The formation of these derivatives was confirmed by NMR spectroscopy and X‐ray cry...

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Detalles Bibliográficos
Autores principales: Drusgala, Manfred, Frühwirt, Philipp, Glotz, Gabriel, Hogrefe, Katharina, Torvisco, Ana, Fischer, Roland C., Wilkening, H. Martin R., Kelterer, Anne‐Marie, Gescheidt, Georg, Haas, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596710/
https://www.ncbi.nlm.nih.gov/pubmed/34464492
http://dx.doi.org/10.1002/anie.202111636

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596710/
https://www.ncbi.nlm.nih.gov/pubmed/34464492
http://dx.doi.org/10.1002/anie.202111636

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