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Thermoneutral N−H Bond Activation of Ammonia by a Geometrically Constrained Phosphine

A geometrically constrained phosphine bearing a tridentate NNS pincer ligand is reported. The effect of the geometric constraint on the electronic structure was probed by theoretical calculations and derivatization reactions. Reactions with N−H bonds result in formation of cooperative addition produ...

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Detalles Bibliográficos
Autores principales:	Abbenseth, Josh, Townrow, Oliver P. E., Goicoechea, Jose M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596738/ https://www.ncbi.nlm.nih.gov/pubmed/34478227 http://dx.doi.org/10.1002/anie.202111017

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