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Noncovalent Axial I⋅⋅⋅Pt⋅⋅⋅I Interactions in Platinum(II) Complexes Strengthen in the Excited State

Coordination compounds of platinum(II) participate in various noncovalent axial interactions involving metal center. Weakly bound axial ligands can be electrophilic or nucleophilic; however, interactions with nucleophiles are compromised by electron density clashing. Consequently, simultaneous axial...

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Detalles Bibliográficos
Autores principales: Bulatov, Evgeny, Eskelinen, Toni, Ivanov, Alexander Yu., Tolstoy, Peter M., Kalenius, Elina, Hirva, Pipsa, Haukka, Matti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596824/
https://www.ncbi.nlm.nih.gov/pubmed/34328257
http://dx.doi.org/10.1002/cphc.202100468