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Reversible Dissociation of a Dialumene

Dialumenes are neutral Al(I) compounds with Al=Al multiple bonds. We report the isolation of an amidophosphine‐supported dialumene. Our X‐ray crystallographic, spectroscopic, and computational DFT analyses reveal a long and extreme trans‐bent Al=Al bond with a low dissociation energy and bond order....

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Detalles Bibliográficos
Autores principales:	Falconer, Rosalyn L., Byrne, Keelan M., Nichol, Gary S., Krämer, Tobias, Cowley, Michael J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596890/ https://www.ncbi.nlm.nih.gov/pubmed/34520616 http://dx.doi.org/10.1002/anie.202111385

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