Lewis Superacidic Tellurenyl Cation‐Induced Electrophilic Activation of an Inert Carborane

The aryltellurenyl cation [2‐(tBuNCH)C(6)H(4)Te](+), a Lewis super acid, and the weakly coordinating carborane anion [CB(11)H(12)](−), an extremely weak Brønsted acid (pK (a)=131.0 in MeCN), form an isolable ion pair complex [2‐(tBuNCH)C(6)H(4)Te][CB(11)H(12)], in which the Brønsted acidity (pK (a)...

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Detalles Bibliográficos
Autores principales: Hejda, Martin, Duvinage, Daniel, Lork, Enno, Lyčka, Antonín, Černošek, Zdeněk, Macháček, Jan, Makarov, Sergey, Ketkov, Sergey, Mebs, Stefan, Dostál, Libor, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596995/
https://www.ncbi.nlm.nih.gov/pubmed/34495561
http://dx.doi.org/10.1002/chem.202103181

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596995/
https://www.ncbi.nlm.nih.gov/pubmed/34495561
http://dx.doi.org/10.1002/chem.202103181

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