Cargando…

Lewis Superacidic Tellurenyl Cation‐Induced Electrophilic Activation of an Inert Carborane

The aryltellurenyl cation [2‐(tBuNCH)C(6)H(4)Te](+), a Lewis super acid, and the weakly coordinating carborane anion [CB(11)H(12)](−), an extremely weak Brønsted acid (pK (a)=131.0 in MeCN), form an isolable ion pair complex [2‐(tBuNCH)C(6)H(4)Te][CB(11)H(12)], in which the Brønsted acidity (pK (a)...

Descripción completa

Detalles Bibliográficos
Autores principales:	Hejda, Martin, Duvinage, Daniel, Lork, Enno, Lyčka, Antonín, Černošek, Zdeněk, Macháček, Jan, Makarov, Sergey, Ketkov, Sergey, Mebs, Stefan, Dostál, Libor, Beckmann, Jens
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596995/ https://www.ncbi.nlm.nih.gov/pubmed/34495561 http://dx.doi.org/10.1002/chem.202103181

Ejemplares similares

Transient Phosphenium and Arsenium Ions versus Stable Stibenium and Bismuthenium Ions
por: Olaru, Marian, et al.
Publicado: (2019)

Al(OCArF3)(3) – a thermally stable Lewis superacid
por: Kögel, Julius F., et al.
Publicado: (2018)

Isolation of an Antiaromatic 9‐Hydroxy Fluorenyl Cation
por: Duvinage, Daniel, et al.
Publicado: (2021)

A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
por: Haupt, Axel, et al.
Publicado: (2021)

Tri‐ and Tetranuclear Metal‐String Complexes with Metallophilic d(10)–d(10) Interactions
por: Olaru, Marian, et al.
Publicado: (2019)

A methylation platform of unconventional inert aryl electrophiles: trimethylboroxine as a universal methylating reagent
por: Feng, Boya, et al.
Publicado: (2020)

Gastric Superacidity Treated by Cholic Acid
Publicado: (1914)

Isolable Silicon‐Based Polycations with Lewis Superacidity
por: Hermannsdorfer, André, et al.
Publicado: (2020)

A free boratriptycene-type Lewis superacid
por: Henkelmann, Marcel, et al.
Publicado: (2021)

Synthesis of 3-Aryl-ortho-carboranes with Sensitive Functional Groups †
por: Anufriev, Sergey A., et al.
Publicado: (2021)

Synthesis of Zwitter-Ionic Conjugate of Nido-Carborane with Cholesterol
por: Druzina, Anna A., et al.
Publicado: (2021)

Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions
por: Olaru, Marian, et al.
Publicado: (2020)

Reactions of 2-carbonyl- and 2-hydroxy(or methoxy)alkyl-substituted benzimidazoles with arenes in the superacid CF(3)SO(3)H. NMR and DFT studies of dicationic electrophilic species
por: Ryabukhin, Dmitry S, et al.
Publicado: (2019)

Mesoporous superacid catalysts for valorisation of refinery naphtha stream
por: Mehla, Sunil, et al.
Publicado: (2018)

Ring Opening Reactions of β‐Propiolactam in Superacidic Media
por: Beck, Stefanie, et al.
Publicado: (2022)

Strengthening of the C−F Bond in Fumaryl Fluoride with Superacids
por: Bayer, Marie C., et al.
Publicado: (2022)

How the Position of Substitution Affects Intermolecular Bonding in Halogen Derivatives of Carboranes: Crystal Structures of 1,2,3- and 8,9,12-Triiodo- and 8,9,12-Tribromo ortho-Carboranes
por: Suponitsky, Kyrill Yu., et al.
Publicado: (2023)

Negishi's Reagent Versus Rosenthal's Reagent in the Formation of Zirconacyclopentadienes
por: Urrego‐Riveros, Sara, et al.
Publicado: (2019)

Bis(6-Diphenylphosphinoacenaphth-5-yl)Telluride as a Ligand toward Manganese and Rhenium Carbonyls
por: Do, Truong Giang, et al.
Publicado: (2018)

Carborane-thiol protected copper nanoclusters: stimuli-responsive materials with tunable phosphorescence
por: Jana, Arijit, et al.
Publicado: (2022)

Preparing (Metalla)carboranes for Nanomedicine
por: Gozzi, Marta, et al.
Publicado: (2021)

Electrochemical Cage Activation of Carboranes
por: Yang, Long, et al.
Publicado: (2022)

Carbonylation of Polyfluorinated 1-Arylalkan-1-ols and Diols in Superacids
por: Wang, Siqi, et al.
Publicado: (2022)

Rearrangements in icosahedral boranes and carboranes revisited
por: Brown, Christopher A., et al.
Publicado: (2006)

Free three-dimensional carborane carbanions
por: Jayaweera, H. D. A. Chathumal, et al.
Publicado: (2021)

Bis(catecholato)silanes: assessing, rationalizing and increasing silicon's Lewis superacidity
por: Hartmann, Deborah, et al.
Publicado: (2019)

Tuning carrier concentration in a superacid treated MoS(2) monolayer
por: Molas, Maciej R., et al.
Publicado: (2019)

Aquivion perfluorosulfonic superacid as an effective catalyst for selective epoxidation of vegetable oils
por: Polese, Riccardo, et al.
Publicado: (2022)

Accelerated reactions of amines with carbon dioxide driven by superacid at the microdroplet interface
por: Huang, Kai-Hung, et al.
Publicado: (2020)

Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid
por: Akram, Manjur O., et al.
Publicado: (2022)

Perfluorinated Trialkoxysilanol with Dramatically Increased Brønsted Acidity
por: Feige, Felix, et al.
Publicado: (2021)

Bis(perchlorocatecholato)germane: Hard and Soft Lewis Superacid with Unlimited Water Stability
por: Roth, Daniel, et al.
Publicado: (2020)

Enhancement of thermoelectric performance of PEDOT:PSS films by post-treatment with a superacid
por: Wang, Xizu, et al.
Publicado: (2018)

Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
por: Fernandes, Anthony J., et al.
Publicado: (2021)

Carborane Stabilized “19-Electron” Molybdenum Metalloradical
por: Jaiswal, Kuldeep, et al.
Publicado: (2021)

Carboranes as unique pharmacophores in antitumor medicinal chemistry
por: Chen, Yu, et al.
Publicado: (2022)

5,5,5-Trichloropent-3-en-one as a Precursor of 1,3-Bi-centered Electrophile in Reactions with Arenes in Brønsted Superacid CF(3)SO(3)H. Synthesis of 3-Methyl-1-trichloromethylindenes
por: Shershnev, Ivan A., et al.
Publicado: (2022)

Calix[4]pyrrolato Stibenium: Lewis Superacidity by Antimony(III)‐Antimony(V) Electromerism
por: Schorpp, Marcel, et al.
Publicado: (2022)

The inert doublet model
por: Arias, C, et al.
Publicado: (2010)

Dextranol: An inert xeroprotectant
por: Jones, Bryan J., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_ndgaam0getp2k6hc2q75i0p5l1