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One‐Step Synthesis and Schlenk‐Type Equilibrium of Cyclopentadienylmagnesium Bromides

In the in situ Grignard metalation method (iGMM), the addition of bromoethane to a suspension of magnesium turnings and cyclopentadienes [C(5)H(6) (HCp), C(5)H(5)‐Si(iPr)(3) (HCp(TIPS))] in diethyl ether smoothly yields heteroleptic [(Et(2)O)Mg(Cp(R))(μ‐Br)](2) (Cp(R)=Cp (1), Cp(TIPS) (2)). The Schl...

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Detalles Bibliográficos
Autores principales:	Schüler, Philipp, Görls, Helmar, Krieck, Sven, Westerhausen, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597043/ https://www.ncbi.nlm.nih.gov/pubmed/34468050 http://dx.doi.org/10.1002/chem.202102636

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