New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices

This work presents for the first time a new diglyme‐based gel polymer (DOBn‐GPE) suitable for Na‐based energy storage devices. The DOBn‐GPE, which contains a methacrylate‐based polymer, exhibited an excellent high ionic conductivity (2.3 mS cm(−1) at 20 °C), broad electrochemical stability (>5.0 ...

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Detalles Bibliográficos
Autores principales: Babu, Binson, Enke, Marcel, Prykhodska, Sofiia, Lex‐Balducci, Alexandra, Schubert, Ulrich S., Balducci, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597054/
https://www.ncbi.nlm.nih.gov/pubmed/34473902
http://dx.doi.org/10.1002/cssc.202101445
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author Babu, Binson
Enke, Marcel
Prykhodska, Sofiia
Lex‐Balducci, Alexandra
Schubert, Ulrich S.
Balducci, Andrea
author_facet Babu, Binson
Enke, Marcel
Prykhodska, Sofiia
Lex‐Balducci, Alexandra
Schubert, Ulrich S.
Balducci, Andrea
author_sort Babu, Binson
collection PubMed
description This work presents for the first time a new diglyme‐based gel polymer (DOBn‐GPE) suitable for Na‐based energy storage devices. The DOBn‐GPE, which contains a methacrylate‐based polymer, exhibited an excellent high ionic conductivity (2.3 mS cm(−1) at 20 °C), broad electrochemical stability (>5.0 V), and high mechanical stability. DOBn‐GPE could be successfully used for the realization of Na‐ion capacitors, sodium‐metal batteries, and sodium‐ion batteries, displaying performance comparable with those of systems containing liquid electrolytes at room temperature and at 60 °C. The results of these investigation indicated that the development of diglyme‐based gel polymer electrolytes represents a promising strategy for the realization of advanced Na‐based energy storage devices.
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spelling pubmed-85970542021-11-22 New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices Babu, Binson Enke, Marcel Prykhodska, Sofiia Lex‐Balducci, Alexandra Schubert, Ulrich S. Balducci, Andrea ChemSusChem Full Papers This work presents for the first time a new diglyme‐based gel polymer (DOBn‐GPE) suitable for Na‐based energy storage devices. The DOBn‐GPE, which contains a methacrylate‐based polymer, exhibited an excellent high ionic conductivity (2.3 mS cm(−1) at 20 °C), broad electrochemical stability (>5.0 V), and high mechanical stability. DOBn‐GPE could be successfully used for the realization of Na‐ion capacitors, sodium‐metal batteries, and sodium‐ion batteries, displaying performance comparable with those of systems containing liquid electrolytes at room temperature and at 60 °C. The results of these investigation indicated that the development of diglyme‐based gel polymer electrolytes represents a promising strategy for the realization of advanced Na‐based energy storage devices. John Wiley and Sons Inc. 2021-09-30 2021-11-04 /pmc/articles/PMC8597054/ /pubmed/34473902 http://dx.doi.org/10.1002/cssc.202101445 Text en © 2021 The Authors. ChemSusChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Babu, Binson
Enke, Marcel
Prykhodska, Sofiia
Lex‐Balducci, Alexandra
Schubert, Ulrich S.
Balducci, Andrea
New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices
title New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices
title_full New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices
title_fullStr New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices
title_full_unstemmed New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices
title_short New Diglyme‐based Gel Polymer Electrolytes for Na‐based Energy Storage Devices
title_sort new diglyme‐based gel polymer electrolytes for na‐based energy storage devices
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597054/
https://www.ncbi.nlm.nih.gov/pubmed/34473902
http://dx.doi.org/10.1002/cssc.202101445
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