Kinetic resolution of sulfur-stereogenic sulfoximines by Pd(ii)–MPAA catalyzed C–H arylation and olefination

A direct Pd(ii)-catalyzed kinetic resolution of heteroaryl-enabled sulfoximines through an ortho-C–H alkenylation/arylation of arenes has been developed. The coordination of the sulfoximine pyridyl-motif and the chiral amino acid MPAA ligand to the Pd(ii)-catalyst controls the enantio-discriminating...

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Detalles Bibliográficos
Autores principales: Mukherjee, Kallol, Grimblat, Nicolas, Sau, Somratan, Ghosh, Koushik, Shankar, Majji, Gandon, Vincent, Sahoo, Akhila K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597855/
https://www.ncbi.nlm.nih.gov/pubmed/34820102
http://dx.doi.org/10.1039/d1sc04299h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597855/
https://www.ncbi.nlm.nih.gov/pubmed/34820102
http://dx.doi.org/10.1039/d1sc04299h

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