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Proofreading experimentally assigned stereochemistry through Q2MM predictions in Pd-catalyzed allylic aminations
The palladium-catalyzed enantioselective allylic substitution by carbon or nitrogen nucleophiles is a key transformation that is particularly useful for the synthesis of bioactive compounds. Unfortunately, the selection of a suitable ligand/substrate combination often requires significant screening...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8602308/ https://www.ncbi.nlm.nih.gov/pubmed/34795274 http://dx.doi.org/10.1038/s41467-021-27065-2 |