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Luminescent First-Row Transition Metal Complexes
[Image: see text] Precious and rare elements have traditionally dominated inorganic photophysics and photochemistry, but now we are witnessing a paradigm shift toward cheaper and more abundant metals. Even though emissive complexes based on selected first-row transition metals have long been known,...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8611671/ https://www.ncbi.nlm.nih.gov/pubmed/34841405 http://dx.doi.org/10.1021/jacsau.1c00353 |
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author | Wegeberg, Christina Wenger, Oliver S. |
author_facet | Wegeberg, Christina Wenger, Oliver S. |
author_sort | Wegeberg, Christina |
collection | PubMed |
description | [Image: see text] Precious and rare elements have traditionally dominated inorganic photophysics and photochemistry, but now we are witnessing a paradigm shift toward cheaper and more abundant metals. Even though emissive complexes based on selected first-row transition metals have long been known, recent conceptual breakthroughs revealed that a much broader range of elements in different oxidation states are useable for this purpose. Coordination compounds of V, Cr, Mn, Fe, Co, Ni, and Cu now show electronically excited states with unexpected reactivity and photoluminescence behavior. Aside from providing a compact survey of the recent conceptual key advances in this dynamic field, our Perspective identifies the main design strategies that enabled the discovery of fundamentally new types of 3d-metal-based luminophores and photosensitizers operating in solution at room temperature. |
format | Online Article Text |
id | pubmed-8611671 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-86116712021-11-26 Luminescent First-Row Transition Metal Complexes Wegeberg, Christina Wenger, Oliver S. JACS Au [Image: see text] Precious and rare elements have traditionally dominated inorganic photophysics and photochemistry, but now we are witnessing a paradigm shift toward cheaper and more abundant metals. Even though emissive complexes based on selected first-row transition metals have long been known, recent conceptual breakthroughs revealed that a much broader range of elements in different oxidation states are useable for this purpose. Coordination compounds of V, Cr, Mn, Fe, Co, Ni, and Cu now show electronically excited states with unexpected reactivity and photoluminescence behavior. Aside from providing a compact survey of the recent conceptual key advances in this dynamic field, our Perspective identifies the main design strategies that enabled the discovery of fundamentally new types of 3d-metal-based luminophores and photosensitizers operating in solution at room temperature. American Chemical Society 2021-09-24 /pmc/articles/PMC8611671/ /pubmed/34841405 http://dx.doi.org/10.1021/jacsau.1c00353 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Wegeberg, Christina Wenger, Oliver S. Luminescent First-Row Transition Metal Complexes |
title | Luminescent First-Row Transition Metal Complexes |
title_full | Luminescent First-Row Transition Metal Complexes |
title_fullStr | Luminescent First-Row Transition Metal Complexes |
title_full_unstemmed | Luminescent First-Row Transition Metal Complexes |
title_short | Luminescent First-Row Transition Metal Complexes |
title_sort | luminescent first-row transition metal complexes |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8611671/ https://www.ncbi.nlm.nih.gov/pubmed/34841405 http://dx.doi.org/10.1021/jacsau.1c00353 |
work_keys_str_mv | AT wegebergchristina luminescentfirstrowtransitionmetalcomplexes AT wengerolivers luminescentfirstrowtransitionmetalcomplexes |