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Room-Temperature Cu(II) Radical-Triggered Alkyne C–H Activation

[Image: see text] A dimeric Cu(II) complex [Cu(II)(2)L(2)(μ(2)-Cl)Cl] (1) built from an asymmetric tridentate ligand (2-(((2-aminocyclohexyl)imino)methyl)-4,6-di-tert-butylphenol) and weakly coordinating anions has been synthesized and structurally characterized. In dichloromethane solution, 1 exist...

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Detalles Bibliográficos
Autores principales: Devonport, Jack, Sully, Lauren, Boudalis, Athanassios K., Hassell-Hart, Storm, Leech, Matthew C., Lam, Kevin, Abdul-Sada, Alaa, Tizzard, Graham J., Coles, Simon J., Spencer, John, Vargas, Alfredo, Kostakis, George E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8611675/
https://www.ncbi.nlm.nih.gov/pubmed/34841411
http://dx.doi.org/10.1021/jacsau.1c00310

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