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Chelation-assisted C–C bond activation of biphenylene by gold(i) halides

A chelation-assisted oxidative addition of gold(i) into the C–C bond of biphenylene is reported here. The presence of a coordinating group (pyridine, phosphine) in the biphenylene unit enabled the use of readily available gold(i) halide precursors providing a new, straightforward entry towards cyclo...

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Detalles Bibliográficos
Autores principales: Beucher, Hélène, Schörgenhumer, Johannes, Merino, Estíbaliz, Nevado, Cristina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8612398/
https://www.ncbi.nlm.nih.gov/pubmed/34909149
http://dx.doi.org/10.1039/d1sc03814a