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Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
[Image: see text] Nitrous oxide (N(2)O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N(2)O directly. It is essential to reduce N(2)O to solve environmental problems. In this study, we investigate the O(2) concentration dependence of N(2...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613805/ https://www.ncbi.nlm.nih.gov/pubmed/34841140 http://dx.doi.org/10.1021/acsomega.1c03365 |
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author | Yun, Jae Geun Lee, Han Min Baik, Gwang Yeol Kim, Ji Yeop Lee, Sang Ji Jeon, Min Kyu Keel, Sang In Hong, Jung Goo |
author_facet | Yun, Jae Geun Lee, Han Min Baik, Gwang Yeol Kim, Ji Yeop Lee, Sang Ji Jeon, Min Kyu Keel, Sang In Hong, Jung Goo |
author_sort | Yun, Jae Geun |
collection | PubMed |
description | [Image: see text] Nitrous oxide (N(2)O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N(2)O directly. It is essential to reduce N(2)O to solve environmental problems. In this study, we investigate the O(2) concentration dependence of N(2)O decomposition under an argon-based gas mixture in a high-temperature thermal reactor. The gas concentrations are calculated using CHEMKIN. The results confirm that more N(2)O is converted to N(2) or NO at lower O(2) concentrations. Therefore, the conversion process is hindered by increasing the O(2) concentration. We propose a modified parameter of N(2)O decomposition, and it is employed in the CHEMKIN calculations. With the modified parameter, the experimental results are in a similar tendency to the calculated results. |
format | Online Article Text |
id | pubmed-8613805 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-86138052021-11-26 Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas Yun, Jae Geun Lee, Han Min Baik, Gwang Yeol Kim, Ji Yeop Lee, Sang Ji Jeon, Min Kyu Keel, Sang In Hong, Jung Goo ACS Omega [Image: see text] Nitrous oxide (N(2)O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N(2)O directly. It is essential to reduce N(2)O to solve environmental problems. In this study, we investigate the O(2) concentration dependence of N(2)O decomposition under an argon-based gas mixture in a high-temperature thermal reactor. The gas concentrations are calculated using CHEMKIN. The results confirm that more N(2)O is converted to N(2) or NO at lower O(2) concentrations. Therefore, the conversion process is hindered by increasing the O(2) concentration. We propose a modified parameter of N(2)O decomposition, and it is employed in the CHEMKIN calculations. With the modified parameter, the experimental results are in a similar tendency to the calculated results. American Chemical Society 2021-11-12 /pmc/articles/PMC8613805/ /pubmed/34841140 http://dx.doi.org/10.1021/acsomega.1c03365 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Yun, Jae Geun Lee, Han Min Baik, Gwang Yeol Kim, Ji Yeop Lee, Sang Ji Jeon, Min Kyu Keel, Sang In Hong, Jung Goo Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas |
title | Effect of the Oxygen Concentration and Temperature
on Thermal Decomposition of N(2)O in an Inert Gas |
title_full | Effect of the Oxygen Concentration and Temperature
on Thermal Decomposition of N(2)O in an Inert Gas |
title_fullStr | Effect of the Oxygen Concentration and Temperature
on Thermal Decomposition of N(2)O in an Inert Gas |
title_full_unstemmed | Effect of the Oxygen Concentration and Temperature
on Thermal Decomposition of N(2)O in an Inert Gas |
title_short | Effect of the Oxygen Concentration and Temperature
on Thermal Decomposition of N(2)O in an Inert Gas |
title_sort | effect of the oxygen concentration and temperature
on thermal decomposition of n(2)o in an inert gas |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613805/ https://www.ncbi.nlm.nih.gov/pubmed/34841140 http://dx.doi.org/10.1021/acsomega.1c03365 |
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