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Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas

[Image: see text] Nitrous oxide (N(2)O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N(2)O directly. It is essential to reduce N(2)O to solve environmental problems. In this study, we investigate the O(2) concentration dependence of N(2...

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Autores principales: Yun, Jae Geun, Lee, Han Min, Baik, Gwang Yeol, Kim, Ji Yeop, Lee, Sang Ji, Jeon, Min Kyu, Keel, Sang In, Hong, Jung Goo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613805/
https://www.ncbi.nlm.nih.gov/pubmed/34841140
http://dx.doi.org/10.1021/acsomega.1c03365
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author Yun, Jae Geun
Lee, Han Min
Baik, Gwang Yeol
Kim, Ji Yeop
Lee, Sang Ji
Jeon, Min Kyu
Keel, Sang In
Hong, Jung Goo
author_facet Yun, Jae Geun
Lee, Han Min
Baik, Gwang Yeol
Kim, Ji Yeop
Lee, Sang Ji
Jeon, Min Kyu
Keel, Sang In
Hong, Jung Goo
author_sort Yun, Jae Geun
collection PubMed
description [Image: see text] Nitrous oxide (N(2)O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N(2)O directly. It is essential to reduce N(2)O to solve environmental problems. In this study, we investigate the O(2) concentration dependence of N(2)O decomposition under an argon-based gas mixture in a high-temperature thermal reactor. The gas concentrations are calculated using CHEMKIN. The results confirm that more N(2)O is converted to N(2) or NO at lower O(2) concentrations. Therefore, the conversion process is hindered by increasing the O(2) concentration. We propose a modified parameter of N(2)O decomposition, and it is employed in the CHEMKIN calculations. With the modified parameter, the experimental results are in a similar tendency to the calculated results.
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spelling pubmed-86138052021-11-26 Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas Yun, Jae Geun Lee, Han Min Baik, Gwang Yeol Kim, Ji Yeop Lee, Sang Ji Jeon, Min Kyu Keel, Sang In Hong, Jung Goo ACS Omega [Image: see text] Nitrous oxide (N(2)O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N(2)O directly. It is essential to reduce N(2)O to solve environmental problems. In this study, we investigate the O(2) concentration dependence of N(2)O decomposition under an argon-based gas mixture in a high-temperature thermal reactor. The gas concentrations are calculated using CHEMKIN. The results confirm that more N(2)O is converted to N(2) or NO at lower O(2) concentrations. Therefore, the conversion process is hindered by increasing the O(2) concentration. We propose a modified parameter of N(2)O decomposition, and it is employed in the CHEMKIN calculations. With the modified parameter, the experimental results are in a similar tendency to the calculated results. American Chemical Society 2021-11-12 /pmc/articles/PMC8613805/ /pubmed/34841140 http://dx.doi.org/10.1021/acsomega.1c03365 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Yun, Jae Geun
Lee, Han Min
Baik, Gwang Yeol
Kim, Ji Yeop
Lee, Sang Ji
Jeon, Min Kyu
Keel, Sang In
Hong, Jung Goo
Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
title Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
title_full Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
title_fullStr Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
title_full_unstemmed Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
title_short Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N(2)O in an Inert Gas
title_sort effect of the oxygen concentration and temperature on thermal decomposition of n(2)o in an inert gas
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613805/
https://www.ncbi.nlm.nih.gov/pubmed/34841140
http://dx.doi.org/10.1021/acsomega.1c03365
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