Cargando…

Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing

[Image: see text] As perceived, fiber-reinforced photocuring resins possess various distinctive advantages over traditional reinforced resin systems. This includes a rapid curing rate, energy efficiency, no volatile organic compounds, high strength, good thermal stability, and chemical resistance. P...

Descripción completa

Detalles Bibliográficos
Autores principales: Desai, Prashil. Dharmesh., Jagtap, Ramanand. Namdev.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613859/
https://www.ncbi.nlm.nih.gov/pubmed/34841154
http://dx.doi.org/10.1021/acsomega.1c04566
_version_ 1784603732619558912
author Desai, Prashil. Dharmesh.
Jagtap, Ramanand. Namdev.
author_facet Desai, Prashil. Dharmesh.
Jagtap, Ramanand. Namdev.
author_sort Desai, Prashil. Dharmesh.
collection PubMed
description [Image: see text] As perceived, fiber-reinforced photocuring resins possess various distinctive advantages over traditional reinforced resin systems. This includes a rapid curing rate, energy efficiency, no volatile organic compounds, high strength, good thermal stability, and chemical resistance. Printing 3D composite objects using vat polymerization techniques has been a center of interest where photocuring resins are applied. In our present study, we have synthesized resorcinol-based diglycidyl ether, that is, a resorcinol-based epoxy resin, and further acrylated to the resorcinol epoxy acrylate oligomer. This oligomer was further formulated to photocuring resins using a suitable quantity of reactive diluents and photoinitiators. Now, three types of synthetic fibers, that is, glass fibers, nylon fibers, and polyester fibers, were incorporated in this formulated resin at different loading percentages. The oligomer synthesized was analyzed for structural conformation using Fourier transform infrared spectroscopy and (13)C nuclear magnetic resonance. Further, we comparatively examined the rheological behavior of prepared formulations, and compatible formulations were applied to stereolithography 3D printers. Finally, physical, mechanical, thermal, transmittance, and morphological characteristics were comparatively analyzed for prepared UV-cured composites. The outcomes obtained during characterizations of UV-cured composites will be inevitably reflected in 3D-printed objects.
format Online
Article
Text
id pubmed-8613859
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-86138592021-11-26 Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing Desai, Prashil. Dharmesh. Jagtap, Ramanand. Namdev. ACS Omega [Image: see text] As perceived, fiber-reinforced photocuring resins possess various distinctive advantages over traditional reinforced resin systems. This includes a rapid curing rate, energy efficiency, no volatile organic compounds, high strength, good thermal stability, and chemical resistance. Printing 3D composite objects using vat polymerization techniques has been a center of interest where photocuring resins are applied. In our present study, we have synthesized resorcinol-based diglycidyl ether, that is, a resorcinol-based epoxy resin, and further acrylated to the resorcinol epoxy acrylate oligomer. This oligomer was further formulated to photocuring resins using a suitable quantity of reactive diluents and photoinitiators. Now, three types of synthetic fibers, that is, glass fibers, nylon fibers, and polyester fibers, were incorporated in this formulated resin at different loading percentages. The oligomer synthesized was analyzed for structural conformation using Fourier transform infrared spectroscopy and (13)C nuclear magnetic resonance. Further, we comparatively examined the rheological behavior of prepared formulations, and compatible formulations were applied to stereolithography 3D printers. Finally, physical, mechanical, thermal, transmittance, and morphological characteristics were comparatively analyzed for prepared UV-cured composites. The outcomes obtained during characterizations of UV-cured composites will be inevitably reflected in 3D-printed objects. American Chemical Society 2021-11-11 /pmc/articles/PMC8613859/ /pubmed/34841154 http://dx.doi.org/10.1021/acsomega.1c04566 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Desai, Prashil. Dharmesh.
Jagtap, Ramanand. Namdev.
Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing
title Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing
title_full Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing
title_fullStr Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing
title_full_unstemmed Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing
title_short Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing
title_sort synthesis and characterization of fiber-reinforced resorcinol epoxy acrylate applied to stereolithography 3d printing
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613859/
https://www.ncbi.nlm.nih.gov/pubmed/34841154
http://dx.doi.org/10.1021/acsomega.1c04566
work_keys_str_mv AT desaiprashildharmesh synthesisandcharacterizationoffiberreinforcedresorcinolepoxyacrylateappliedtostereolithography3dprinting
AT jagtapramanandnamdev synthesisandcharacterizationoffiberreinforcedresorcinolepoxyacrylateappliedtostereolithography3dprinting