Cargando…

Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification

[Image: see text] Solubility of hydrogen sulfide (H(2)S) in 46 single and blended physical absorbents, amines, ionic liquids, and hybrid absorbents of amines + ionic liquids and amines + physical absorbents was successfully predicted based on artificial neural networks (ANNs). Three neural network a...

Descripción completa

Detalles Bibliográficos
Autores principales: Nimmanterdwong, Prathana, Changpun, Rachaneeporn, Janthboon, Patipon, Nakrak, Sukanya, Gao, Hongxia, Liang, Zhiwu, Tontiwachwuthikul, Paitoon, Sema, Teerawat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613862/
https://www.ncbi.nlm.nih.gov/pubmed/34841175
http://dx.doi.org/10.1021/acsomega.1c05169
_version_ 1784603733348319232
author Nimmanterdwong, Prathana
Changpun, Rachaneeporn
Janthboon, Patipon
Nakrak, Sukanya
Gao, Hongxia
Liang, Zhiwu
Tontiwachwuthikul, Paitoon
Sema, Teerawat
author_facet Nimmanterdwong, Prathana
Changpun, Rachaneeporn
Janthboon, Patipon
Nakrak, Sukanya
Gao, Hongxia
Liang, Zhiwu
Tontiwachwuthikul, Paitoon
Sema, Teerawat
author_sort Nimmanterdwong, Prathana
collection PubMed
description [Image: see text] Solubility of hydrogen sulfide (H(2)S) in 46 single and blended physical absorbents, amines, ionic liquids, and hybrid absorbents of amines + ionic liquids and amines + physical absorbents was successfully predicted based on artificial neural networks (ANNs). Three neural network algorithms of Levenberg–Marquardt (LM), Bayesian regularization (BR), and scaled conjugate gradient (SCG) were applied for architecting the ANN models. The results showed that both the number of hidden neurons and the prediction algorithm affected the prediction of H(2)S solubility. Based on the mean square error (MSE) and determination coefficient (R(2)), the most attractive model was the LM-ANN model with 17 hidden neurons. As a result, very satisfactory prediction performance (for the testing data set) with an MSE of 0.0014 and an R(2) of 0.9817 was obtained from the developed LM-ANN model. Additionally, a parity chart confirmed that the predicted solubility of H(2)S well aligned with the experimental data. To effectively absorb H(2)S and maintain high solubility of H(2)S, the absorbent should be well complied with the operating pressure. For a low-pressure range of less than 100 kPa, amines are very attractive. As the pressure elevated to 100–1000 kPa, amines and hybrid amine + physical absorbents are suggested. Lastly, at a high pressure over 1000 kPa, physical absorbents and ionic liquids are recommended.
format Online
Article
Text
id pubmed-8613862
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-86138622021-11-26 Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification Nimmanterdwong, Prathana Changpun, Rachaneeporn Janthboon, Patipon Nakrak, Sukanya Gao, Hongxia Liang, Zhiwu Tontiwachwuthikul, Paitoon Sema, Teerawat ACS Omega [Image: see text] Solubility of hydrogen sulfide (H(2)S) in 46 single and blended physical absorbents, amines, ionic liquids, and hybrid absorbents of amines + ionic liquids and amines + physical absorbents was successfully predicted based on artificial neural networks (ANNs). Three neural network algorithms of Levenberg–Marquardt (LM), Bayesian regularization (BR), and scaled conjugate gradient (SCG) were applied for architecting the ANN models. The results showed that both the number of hidden neurons and the prediction algorithm affected the prediction of H(2)S solubility. Based on the mean square error (MSE) and determination coefficient (R(2)), the most attractive model was the LM-ANN model with 17 hidden neurons. As a result, very satisfactory prediction performance (for the testing data set) with an MSE of 0.0014 and an R(2) of 0.9817 was obtained from the developed LM-ANN model. Additionally, a parity chart confirmed that the predicted solubility of H(2)S well aligned with the experimental data. To effectively absorb H(2)S and maintain high solubility of H(2)S, the absorbent should be well complied with the operating pressure. For a low-pressure range of less than 100 kPa, amines are very attractive. As the pressure elevated to 100–1000 kPa, amines and hybrid amine + physical absorbents are suggested. Lastly, at a high pressure over 1000 kPa, physical absorbents and ionic liquids are recommended. American Chemical Society 2021-11-10 /pmc/articles/PMC8613862/ /pubmed/34841175 http://dx.doi.org/10.1021/acsomega.1c05169 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Nimmanterdwong, Prathana
Changpun, Rachaneeporn
Janthboon, Patipon
Nakrak, Sukanya
Gao, Hongxia
Liang, Zhiwu
Tontiwachwuthikul, Paitoon
Sema, Teerawat
Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification
title Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification
title_full Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification
title_fullStr Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification
title_full_unstemmed Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification
title_short Applied Artificial Neural Network for Hydrogen Sulfide Solubility in Natural Gas Purification
title_sort applied artificial neural network for hydrogen sulfide solubility in natural gas purification
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613862/
https://www.ncbi.nlm.nih.gov/pubmed/34841175
http://dx.doi.org/10.1021/acsomega.1c05169
work_keys_str_mv AT nimmanterdwongprathana appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT changpunrachaneeporn appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT janthboonpatipon appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT nakraksukanya appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT gaohongxia appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT liangzhiwu appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT tontiwachwuthikulpaitoon appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification
AT semateerawat appliedartificialneuralnetworkforhydrogensulfidesolubilityinnaturalgaspurification