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Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly

The existence of ferroelectricity and ferromagnetism in multiferroic materials and their coupling enables the manipulation of the electric polarization with applied magnetic field and vice versa, opening many doors for the practical applications. However, the preparation of polymeric multiferroic na...

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Detalles Bibliográficos
Autores principales: Terzić, Ivan, Meereboer, Niels L., Mellema, Harm Hendrik, Loos, Katja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613863/
https://www.ncbi.nlm.nih.gov/pubmed/34912561
http://dx.doi.org/10.1039/c8tc05017a
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author Terzić, Ivan
Meereboer, Niels L.
Mellema, Harm Hendrik
Loos, Katja
author_facet Terzić, Ivan
Meereboer, Niels L.
Mellema, Harm Hendrik
Loos, Katja
author_sort Terzić, Ivan
collection PubMed
description The existence of ferroelectricity and ferromagnetism in multiferroic materials and their coupling enables the manipulation of the electric polarization with applied magnetic field and vice versa, opening many doors for the practical applications. However, the preparation of polymeric multiferroic nanocomposites is often accompanied with aggregation of magnetic particles inside the ferroelectric polymeric matrix. To overcome this issue, we developed a simple and straightforward method to obtain multiferroic nanocomposites with an exceptional and selective dispersion of magnetic nanoparticles, using self-assembly of poly(vinylidene fluoride) (PVDF)-based block copolymers. Magnetic cobalt ferrite nanoparticles modified with gallic acid are selectively incorporated within poly(2-vinylpyridine) (P2VP) domains of the lamellar block copolymer due to strong hydrogen bond formation between the ligand and the P2VP block. Using this approach, phase separation between the blocks is improved, which leads to an increase in the degree of crystallinity, whereas the selective dispersion of nanoparticles inside amorphous domains prevents changes in the crystalline phase of the ferroelectric block. The obtained nanocomposites demonstrate both ferroelectric and magnetic properties without large conductive losses at high electric field, making them good candidates for improved multiferroic devices.
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spelling pubmed-86138632021-12-13 Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly Terzić, Ivan Meereboer, Niels L. Mellema, Harm Hendrik Loos, Katja J Mater Chem C Mater Chemistry The existence of ferroelectricity and ferromagnetism in multiferroic materials and their coupling enables the manipulation of the electric polarization with applied magnetic field and vice versa, opening many doors for the practical applications. However, the preparation of polymeric multiferroic nanocomposites is often accompanied with aggregation of magnetic particles inside the ferroelectric polymeric matrix. To overcome this issue, we developed a simple and straightforward method to obtain multiferroic nanocomposites with an exceptional and selective dispersion of magnetic nanoparticles, using self-assembly of poly(vinylidene fluoride) (PVDF)-based block copolymers. Magnetic cobalt ferrite nanoparticles modified with gallic acid are selectively incorporated within poly(2-vinylpyridine) (P2VP) domains of the lamellar block copolymer due to strong hydrogen bond formation between the ligand and the P2VP block. Using this approach, phase separation between the blocks is improved, which leads to an increase in the degree of crystallinity, whereas the selective dispersion of nanoparticles inside amorphous domains prevents changes in the crystalline phase of the ferroelectric block. The obtained nanocomposites demonstrate both ferroelectric and magnetic properties without large conductive losses at high electric field, making them good candidates for improved multiferroic devices. The Royal Society of Chemistry 2018-12-21 /pmc/articles/PMC8613863/ /pubmed/34912561 http://dx.doi.org/10.1039/c8tc05017a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Terzić, Ivan
Meereboer, Niels L.
Mellema, Harm Hendrik
Loos, Katja
Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
title Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
title_full Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
title_fullStr Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
title_full_unstemmed Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
title_short Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
title_sort polymer-based multiferroic nanocomposites via directed block copolymer self-assembly
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8613863/
https://www.ncbi.nlm.nih.gov/pubmed/34912561
http://dx.doi.org/10.1039/c8tc05017a
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