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Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater

The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that E(corr) and R(f) increased while i(pass) and weight loss rate decreased as the pH...

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Autores principales: Zhang, Yingxiao, Yan, Tingting, Fan, Lin, Liu, Zhiyong, Song, Longfei, Li, Xiaogang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8617934/
https://www.ncbi.nlm.nih.gov/pubmed/34832166
http://dx.doi.org/10.3390/ma14226764
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author Zhang, Yingxiao
Yan, Tingting
Fan, Lin
Liu, Zhiyong
Song, Longfei
Li, Xiaogang
author_facet Zhang, Yingxiao
Yan, Tingting
Fan, Lin
Liu, Zhiyong
Song, Longfei
Li, Xiaogang
author_sort Zhang, Yingxiao
collection PubMed
description The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that E(corr) and R(f) increased while i(pass) and weight loss rate decreased as the pH of simulated seawater increased. The TA2 passive film was determined to be mainly composed of a large amount of TiO(2) and a small amount of TiO. The repassivation function of TA2 can be expressed as E = −0.1375 + 0.0532ln(t − 1.241) for a simulated seawater pH of 8.2. The parameter b, which represents the slope of the potential–time curve during the friction electrode test, was used to evaluate the repassivation behavior of TA2. The increase in pH value was observed to promote the repassivation speed of the passive film, which is beneficial to the corrosion resistance of TA2.
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spelling pubmed-86179342021-11-27 Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater Zhang, Yingxiao Yan, Tingting Fan, Lin Liu, Zhiyong Song, Longfei Li, Xiaogang Materials (Basel) Article The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that E(corr) and R(f) increased while i(pass) and weight loss rate decreased as the pH of simulated seawater increased. The TA2 passive film was determined to be mainly composed of a large amount of TiO(2) and a small amount of TiO. The repassivation function of TA2 can be expressed as E = −0.1375 + 0.0532ln(t − 1.241) for a simulated seawater pH of 8.2. The parameter b, which represents the slope of the potential–time curve during the friction electrode test, was used to evaluate the repassivation behavior of TA2. The increase in pH value was observed to promote the repassivation speed of the passive film, which is beneficial to the corrosion resistance of TA2. MDPI 2021-11-10 /pmc/articles/PMC8617934/ /pubmed/34832166 http://dx.doi.org/10.3390/ma14226764 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Yingxiao
Yan, Tingting
Fan, Lin
Liu, Zhiyong
Song, Longfei
Li, Xiaogang
Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_full Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_fullStr Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_full_unstemmed Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_short Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_sort effect of ph on the corrosion and repassivation behavior of ta2 in simulated seawater
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8617934/
https://www.ncbi.nlm.nih.gov/pubmed/34832166
http://dx.doi.org/10.3390/ma14226764
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