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Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures

The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g(−1)) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have been carried out. Th...

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Autores principales: Liu, Baoyou, Wang, Xinyu, Tian, Jie, Zhang, Peiwen, Yang, Huilong, Jin, Nanxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8620407/
https://www.ncbi.nlm.nih.gov/pubmed/34834045
http://dx.doi.org/10.3390/molecules26226953
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author Liu, Baoyou
Wang, Xinyu
Tian, Jie
Zhang, Peiwen
Yang, Huilong
Jin, Nanxi
author_facet Liu, Baoyou
Wang, Xinyu
Tian, Jie
Zhang, Peiwen
Yang, Huilong
Jin, Nanxi
author_sort Liu, Baoyou
collection PubMed
description The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g(−1)) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have been carried out. The molar fraction of [EMIM] [TFA] dependence of the viscosity and absorption capacity was demonstrated. The addition of a small amount of [EMIM] [TFA] into TEA led to rapidly decreased rates of binary blends’ viscosity and absorption capacity. However, the viscosity and absorption of binary blends did not decrease significantly when [EMIM] [TFA] was increased to a specific value. Compared with the molar fraction of the solution, the temperature had no obvious effect on viscosity and absorption capacity. By modeling and optimizing the ratio of viscosity and absorption capacity of ([EMIM] [TFA] + TEA), it is proven that when the mole fraction of [EMIM] [TFA] is 0.58, ([EMIM] [TFA] + TEA) has the best viscosity and absorption capacity at the same time. In addition, at 303.15 K, ([EMIM] [TFA] + TEA) was absorbed and desorbed six times, the absorption slightly decreased, and the desorption increased.
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spelling pubmed-86204072021-11-27 Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures Liu, Baoyou Wang, Xinyu Tian, Jie Zhang, Peiwen Yang, Huilong Jin, Nanxi Molecules Article The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g(−1)) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have been carried out. The molar fraction of [EMIM] [TFA] dependence of the viscosity and absorption capacity was demonstrated. The addition of a small amount of [EMIM] [TFA] into TEA led to rapidly decreased rates of binary blends’ viscosity and absorption capacity. However, the viscosity and absorption of binary blends did not decrease significantly when [EMIM] [TFA] was increased to a specific value. Compared with the molar fraction of the solution, the temperature had no obvious effect on viscosity and absorption capacity. By modeling and optimizing the ratio of viscosity and absorption capacity of ([EMIM] [TFA] + TEA), it is proven that when the mole fraction of [EMIM] [TFA] is 0.58, ([EMIM] [TFA] + TEA) has the best viscosity and absorption capacity at the same time. In addition, at 303.15 K, ([EMIM] [TFA] + TEA) was absorbed and desorbed six times, the absorption slightly decreased, and the desorption increased. MDPI 2021-11-18 /pmc/articles/PMC8620407/ /pubmed/34834045 http://dx.doi.org/10.3390/molecules26226953 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liu, Baoyou
Wang, Xinyu
Tian, Jie
Zhang, Peiwen
Yang, Huilong
Jin, Nanxi
Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_full Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_fullStr Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_full_unstemmed Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_short Experimental Research on NO(2) Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_sort experimental research on no(2) viscosity and absorption for (1-ethyl-3-methylimidazolium trifluoroacetate + triethanolamine) binary mixtures
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8620407/
https://www.ncbi.nlm.nih.gov/pubmed/34834045
http://dx.doi.org/10.3390/molecules26226953
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