Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions

A stable, earth-abundant, reusable cobalt-based heterogeneous catalyst is developed for the oxidative esterification of alcohols under ambient conditions, featuring broad substrate scope, providing good to excellent product yields. This protocol enables easy recyclability of the catalyst, measured u...

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Detalles Bibliográficos
Autores principales: Zhou, Changjian, Sun, Rong, Zhang, Yuting, Xiong, Biao, Dai, Hui, Dai, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8622685/
https://www.ncbi.nlm.nih.gov/pubmed/34833882
http://dx.doi.org/10.3390/molecules26226792
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author Zhou, Changjian
Sun, Rong
Zhang, Yuting
Xiong, Biao
Dai, Hui
Dai, Yong
author_facet Zhou, Changjian
Sun, Rong
Zhang, Yuting
Xiong, Biao
Dai, Hui
Dai, Yong
author_sort Zhou, Changjian
collection PubMed
description A stable, earth-abundant, reusable cobalt-based heterogeneous catalyst is developed for the oxidative esterification of alcohols under ambient conditions, featuring broad substrate scope, providing good to excellent product yields. This protocol enables easy recyclability of the catalyst, measured up to five times without significant loss of efficiency. The active sites of Co-N-Si/AC are proposed to be Co-N species.
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spelling pubmed-86226852021-11-27 Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions Zhou, Changjian Sun, Rong Zhang, Yuting Xiong, Biao Dai, Hui Dai, Yong Molecules Article A stable, earth-abundant, reusable cobalt-based heterogeneous catalyst is developed for the oxidative esterification of alcohols under ambient conditions, featuring broad substrate scope, providing good to excellent product yields. This protocol enables easy recyclability of the catalyst, measured up to five times without significant loss of efficiency. The active sites of Co-N-Si/AC are proposed to be Co-N species. MDPI 2021-11-10 /pmc/articles/PMC8622685/ /pubmed/34833882 http://dx.doi.org/10.3390/molecules26226792 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhou, Changjian
Sun, Rong
Zhang, Yuting
Xiong, Biao
Dai, Hui
Dai, Yong
Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_full Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_fullStr Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_full_unstemmed Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_short Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_sort co-n-si/ac catalyst for aerobic oxidation of benzyl alcohols to esters under mild conditions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8622685/
https://www.ncbi.nlm.nih.gov/pubmed/34833882
http://dx.doi.org/10.3390/molecules26226792
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