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Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
Yields of carbonaceous char with a high surface area were enhanced by decreasing the temperature to improve the conversion of hazardous plastic polypropylene (PP), the major component in abundantly used isolation gowns. This study applied pyrolysis with different low pyrolytic temperatures to conver...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8622896/ https://www.ncbi.nlm.nih.gov/pubmed/34833277 http://dx.doi.org/10.3390/polym13223980 |
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author | Harussani, M. M. Rashid, Umer Sapuan, S. M. Abdan, Khalina |
author_facet | Harussani, M. M. Rashid, Umer Sapuan, S. M. Abdan, Khalina |
author_sort | Harussani, M. M. |
collection | PubMed |
description | Yields of carbonaceous char with a high surface area were enhanced by decreasing the temperature to improve the conversion of hazardous plastic polypropylene (PP), the major component in abundantly used isolation gowns. This study applied pyrolysis with different low pyrolytic temperatures to convert disinfected PP-based isolation gown waste (PP-IG) into an optimised amount of char yields. A batch reactor with a horizontal furnace was used to mediate the thermal decomposition of PP-IG. Enhanced surface area and porosity value of PP-IG derived char were obtained via an optimised slow pyrolysis approach. The results showed that the amount of yielded char was inversely proportional to the temperature. This process relied heavily on the process parameters, especially pyrolytic temperature. Additionally, as the heating rate decreased, as well as longer isothermal residence time, the char yields were increased. Optimised temperature for maximum char yields was recorded. The enhanced SBET values for the char and its pore volume were collected, ~24 m(2) g(−1) and ~0.08 cm(3) g(−1), respectively. The char obtained at higher temperatures display higher volatilisation and carbonisation. These findings are beneficial for the utilisation of this pyrolysis model in plastic waste management and conversion of PP-IG waste into char for further activated carbon and fuel briquettes applications, with the enhanced char yields, amidst the COVID-19 pandemic. |
format | Online Article Text |
id | pubmed-8622896 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-86228962021-11-27 Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char Harussani, M. M. Rashid, Umer Sapuan, S. M. Abdan, Khalina Polymers (Basel) Article Yields of carbonaceous char with a high surface area were enhanced by decreasing the temperature to improve the conversion of hazardous plastic polypropylene (PP), the major component in abundantly used isolation gowns. This study applied pyrolysis with different low pyrolytic temperatures to convert disinfected PP-based isolation gown waste (PP-IG) into an optimised amount of char yields. A batch reactor with a horizontal furnace was used to mediate the thermal decomposition of PP-IG. Enhanced surface area and porosity value of PP-IG derived char were obtained via an optimised slow pyrolysis approach. The results showed that the amount of yielded char was inversely proportional to the temperature. This process relied heavily on the process parameters, especially pyrolytic temperature. Additionally, as the heating rate decreased, as well as longer isothermal residence time, the char yields were increased. Optimised temperature for maximum char yields was recorded. The enhanced SBET values for the char and its pore volume were collected, ~24 m(2) g(−1) and ~0.08 cm(3) g(−1), respectively. The char obtained at higher temperatures display higher volatilisation and carbonisation. These findings are beneficial for the utilisation of this pyrolysis model in plastic waste management and conversion of PP-IG waste into char for further activated carbon and fuel briquettes applications, with the enhanced char yields, amidst the COVID-19 pandemic. MDPI 2021-11-17 /pmc/articles/PMC8622896/ /pubmed/34833277 http://dx.doi.org/10.3390/polym13223980 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Harussani, M. M. Rashid, Umer Sapuan, S. M. Abdan, Khalina Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char |
title | Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char |
title_full | Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char |
title_fullStr | Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char |
title_full_unstemmed | Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char |
title_short | Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char |
title_sort | low-temperature thermal degradation of disinfected covid-19 non-woven polypropylene—based isolation gown wastes into carbonaceous char |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8622896/ https://www.ncbi.nlm.nih.gov/pubmed/34833277 http://dx.doi.org/10.3390/polym13223980 |
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